Spinel/Layered Heterostructured Cathode Material for High-Capacity and High-Rate Li-Ion Batteries

被引：279
作者：
Wu, Feng [1 ,2 ]
Li, Ning [1 ,2 ]
Su, Yuefeng [1 ,2 ]
Shou, Haofang [1 ,2 ]
Bao, Liying [1 ,2 ]
Yang, Wen [3 ]
Zhang, Linjing [1 ,2 ]
An, Ran [1 ,2 ]
Chen, Shi [1 ,2 ]
机构：
[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing Key Lab Environm Sci & Engn, Beijing 100081, Peoples R China
[2] Natl Dev Ctr High Technol Green Mat Beijing, Beijing 100081, Peoples R China
[3] Beijing Inst Technol, Sch Chem, Beijing 100081, Peoples R China
来源：
ADVANCED MATERIALS | 2013年 / 25卷 / 27期
基金：
中国国家自然科学基金;
关键词：
cathodes; electrochemistry; heterostructures; lithium ion batteries; spinels; layered materials; HIGH-ENERGY; OXIDE ELECTRODES; RATE CAPABILITY; CO ELECTRODES; HIGH-VOLTAGE; LITHIUM; SPINEL; PERFORMANCE; MN; NI;
D O I：
10.1002/adma.201300598
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Best of both worlds: A heterostructured material is synthesized that comprises a core of layered lithium-rich material and an outer layer of nanospinel material. This spinel/layered heterostructured material maximizes the inherent advantages of the 3D Li+ insertion/extraction framework of the spinel structure and the high Li+ storage capacity of the layered structure. The material exhibits super-high reversible capacities, outstanding rate capability and excellent cycling ability. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3722 / 3726
页数：5
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