Singular orange emission in Zn2SnO4:Eu3+

被引:5
|
作者
Gupta, Santosh K. [1 ]
Sudarshan, K. [1 ,2 ]
Kadam, R. M. [1 ,2 ]
机构
[1] Bhabha Atom Res Ctr, Radiochem Div, Mumbai 400085, Maharashtra, India
[2] Homi Bhabha Natl Inst, Mumbai 400094, Maharashtra, India
关键词
Zn2SnO4; Defects; Singular emission; Luminescence; Europium; Positron annihilation; SINGLE-CRYSTAL; NANOPARTICLES; PHOTOLUMINESCENCE;
D O I
10.1016/j.matlet.2020.128511
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Considering the positive implication of designing singular emitting phosphor in the area of bioimaging and solid state lighting, this work reports on singular orange emission from Zn2SnO4:Eu3+ (ZSOE) phosphor. The studies showed that ZSOE is stabilized in inverse spinel structure with Eu getting stabilized in octahedral Zn sites with orthorhombic symmetry and D-2h point group leading to very intense orange emission with negligible red component. Undoped Zn2SnO4 (ZSO) on ultraviolet irradiation depicted defect induced blue emission due to synergetic effect of F-centers and vacancy clusters. (C) 2020 Elsevier B.V. All rights reserved.
引用
收藏
页数:4
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