Thermal decomposition of 4-fluorobenzenediazonium perfluoroorganyl(fluoro)borates, [4-FC6H4N2]Y (Y = RFBF3 (RF = C6F5, C6F13, trans-C4F9CF=CF, cis-C6F13CF=CF, CF3CC) and (C6F13)2BF2)

被引：2

作者：

Bardin, Vadim V. ^{[1
]}

Frohn, Hermann-Josef ^{[2
]}

机构：

[1] RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, SB, Novosibirsk 630090, Russia

[2] Univ Duisburg Essen, D-47048 Duisburg, Germany

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2013年 / 156卷

关键词：

Arenediazonium salts; Thermal decomposition; DSC analysis; NMR spectroscopy; XENON DIFLUORIDE; SPECTROSCOPIC CHARACTERIZATION; (FLUOROORGANO)FLUOROBORANES; SALTS; FLUOROORGANO; REACTIVITY;

D O I：

10.1016/j.jfluchem.2013.08.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heating of the neat salts [4-FC6H4N2][RFRF3] (R-F = C6F5, C6F13 trans-C4F9CF=CF, cis-C6F13CF=CF, CF3C C or in solid mixtures with NaF gives the principal product 1,4-C6F2H4 besides RFBF2 or Na[RFBF3], respectively. Thermolysis of [4-FC6H4N2][(C6F13)(2)BF2] in NaF results in 1,4-C6F2H4, Na[BF4], Na[(C6F13)(2)BF2], and a new type of product, the isomer Na[C6F13CF(BF3)C5F11]. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：333 / 338

页数：6

共 46 条

[11] Copolymerization of norbornene with styrene catalyzed by Ni{CF3C(O)CHC[N(naphthyl)]CH3}2/B(C6F5)3 and transparent films
Xing, Yuepeng
Chen, Yiwang
He, Xiaohui
JOURNAL OF POLYMER ENGINEERING, 2012, 32 (01) : 7 - 12
[12] Synthesis and Structures of Bidentate Lewis Acid Complexes R[OB(C6F5)2]2 (R = C2H4, p-C6H4) with Pyrazine
Kudina, P. I.
Kryukova, M. A.
Kazakov, I. V.
JOURNAL OF STRUCTURAL CHEMISTRY, 2025, 66 (02) : 346 - 352
[13] Baeyer-Villiger Oxidation and Oxidative Cascade Reactions with Aqueous Hydrogen Peroxide Catalyzed by Lipophilic Li[B(C6F5)4] and Ca[B(C6F5)4]2
Uyanik, Muhammet
Nakashima, Daisuke
Ishihara, Kazuaki
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (36) : 9093 - 9096
[14] REACTIONS OF DINUCLEAR AND POLYNUCLEAR COMPLEXES .12. SYNTHESIS AND THERMAL-DECOMPOSITION REACTIONS OF TETRANUCLEAR CLUSTERS [CO4CP2(CO)5-NLN(RC2R')] (L=PPH2H N=0, 1 OR 2) (R=R'=CF3, C6F5, C6H5 OR ME R=H, R'=CF3)
QUENECH, P
RUMIN, R
PETILLON, FY
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 479 (1-2) : 93 - 102
[15] Two New Types of Xenon-Carbon Species: The Zwitterion, 1-(Xe+)C6F4-4-(BF3-), and the Dication, [1,4-(Xe)2C6F4]2+
Frohn, Hermann-Josef
Bilir, Vural
Westphal, Ulrich
INORGANIC CHEMISTRY, 2012, 51 (21) : 11251 - 11258
[16] Synthesis and Properties of [Cp2Ti(Me)(H2O)][B(C6F5)4]
Dunlop-Briere, Alexandre F.
Baird, Michael C.
ORGANOMETALLICS, 2010, 29 (22) : 6117 - 6120
[17] The Highly Lewis Acidic Dicationic Phosphonium Salt: [(SIMes) PFPh2][B(C6F5)4]2
Holthausen, Michael H.
Mehta, Meera
Stephan, Douglas W.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (25) : 6538 - 6541
[18] Colorless organometallic ionic liquids from cationic ruthenium sandwich complexes: thermal properties, liquid properties, and crystal structures of [Ru(η5-C5H5)(η6-C6H5R)][X] (X = N(SO2CF3)2, N(SO2F)2, PF6)
Komurasaki, Aina
Funasako, Yusuke
Mochida, Tomoyuki
DALTON TRANSACTIONS, 2015, 44 (16) : 7595 - 7605
[19] Synthesis and characterization of novel carbacylamidophosphate derivatives:: Crystal structures of (CF3)C(O)NHP(O)(NC6H12)2, (p-Br-C6H4)C(O)NHP(O)(NC6H12)2 and (p-Cl-C6H4)C(O)NHP(O)(NC6H12)2
Gholivand, K.
Mojahed, F.
Alizadehgan, A. M.
POLISH JOURNAL OF CHEMISTRY, 2007, 81 (10) : 1829 - 1839
[20] Detailed Density Functional Theory Study of the Cationic Zirconocene Compound [Cp(C5H4CMe2C6H4F)ZrMe]+
Sassmannshausen, Joerg
ACS OMEGA, 2022, : 35136 - 35152

← 1 2 3 4 5 →