Thermal decomposition of 4-fluorobenzenediazonium perfluoroorganyl(fluoro)borates, [4-FC6H4N2]Y (Y = RFBF3 (RF = C6F5, C6F13, trans-C4F9CF=CF, cis-C6F13CF=CF, CF3CC) and (C6F13)2BF2)

被引：2
|
作者：
Bardin, Vadim V. [1 ]
Frohn, Hermann-Josef [2 ]
机构：
[1] RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, SB, Novosibirsk 630090, Russia
[2] Univ Duisburg Essen, D-47048 Duisburg, Germany
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2013年 / 156卷
关键词：
Arenediazonium salts; Thermal decomposition; DSC analysis; NMR spectroscopy; XENON DIFLUORIDE; SPECTROSCOPIC CHARACTERIZATION; (FLUOROORGANO)FLUOROBORANES; SALTS; FLUOROORGANO; REACTIVITY;
D O I：
10.1016/j.jfluchem.2013.08.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Heating of the neat salts [4-FC6H4N2][RFRF3] (R-F = C6F5, C6F13 trans-C4F9CF=CF, cis-C6F13CF=CF, CF3C C or in solid mixtures with NaF gives the principal product 1,4-C6F2H4 besides RFBF2 or Na[RFBF3], respectively. Thermolysis of [4-FC6H4N2][(C6F13)(2)BF2] in NaF results in 1,4-C6F2H4, Na[BF4], Na[(C6F13)(2)BF2], and a new type of product, the isomer Na[C6F13CF(BF3)C5F11]. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：333 / 338
页数：6
相关论文
共 46 条
  • [1] Thermoanalytical and preparative investigations of the decomposition of potassium perfluoroorganyl(fluoro)borate salts, K[RFBF3] (RF = perfluoroalkyl, -alkenyl, -alkynyl, and -aryl groups) and K[(RF)2BF2] (RF = C6F5 and C6F13)
    Bardin, Vadim V.
    Shundrina, Inna K.
    Frohn, Hermann-Josef
    JOURNAL OF FLUORINE CHEMISTRY, 2014, 157 : 73 - 78
  • [2] Ab Initio calculation of molecular, thermodynamic, and kinetic parameters of CF, CF2, CF3, and C2F5 radicals and CF4, CF3I, C2F4, and C2F6 molecules in gas
    Skorobogatov, G. A.
    Baranovskii, V. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2011, 81 (11) : 2262 - 2272
  • [3] Quantum-chemical simulation of the gas-phase molecular, thermodynamic, and kinetic parameters of CF, CF2, and CF3 radicals and CF4, C2F2, C2F4, and C2F6 molecules
    Baranovskii, V. I.
    Skorobogatov, G. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2016, 86 (02) : 241 - 250
  • [4] SYNTHESIS AND CHARACTERIZATION OF ARYL(TRIFLUOROMETHYL)BISMUTH COMPOUNDS (R-C6H4)(3-N)BI(CF3)(N) [R=H, 4-CH3, 4-CF3, 3-F, 4-F N=1 AND 2] AND THE REACTIONS OF (C6H5)(3-N)BI(CF3)(N) [N=0-3] WITH BENZOYLPYRIDINIUM CHLORIDE
    KIRIJ, NV
    PASENOK, SV
    YAGUPOLSKII, YL
    NAUMANN, D
    TYRRA, W
    JOURNAL OF FLUORINE CHEMISTRY, 1994, 69 (03) : 219 - 223
  • [5] Xenon(IV)-Carbon Bond of [C6F5XeF2]+; Structural Characterization and Bonding of [C6F5XeF2][BF4], [C6F5XeF2}[BF4]•2HF, and [C6F5XeF2][BF4]•nNCCH 3 (n=1, 2); and the Fluorinating Properties of [C6F5XeF2][BF4]
    Koppe, Karsten
    Haner, Jamie
    Mercier, Helene P. A.
    Frohn, Hermann-J.
    Schrobilgen, Gary J.
    INORGANIC CHEMISTRY, 2014, 53 (21) : 11640 - 11661
  • [6] [(C6F5)2IF2][BF4], the first salt with the electrophilic cation [(C6F5)2IF2]+:: Synthesis, reactivity, and structure
    Frohn, Hermann-Josef
    Wenda, Andre
    Floerke, Ulrich
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (04): : 764 - 770
  • [7] The Difluoromethylated Organogold(III) Complex cis-[Au(PCy3)(4-F-C6H4)(CF2H)(CI)]: Preparation, Characterization, and Its C(sp2)-CF2H Reductive Elimination
    Liu, Shuanshuan
    Kang, Kai
    Liu, Shihan
    Wang, Decai
    Wei, Ping
    Lan, Yu
    Shen, Qilong
    ORGANOMETALLICS, 2018, 37 (21) : 3901 - 3908
  • [8] Phosphido-Bridged Di- and Trinuclear Palladium Complexes from Electron-Poor Phosphanes R2PH (R = C2F5, C6F5, (CF3)2C6H3)
    Bader, Julia
    Neumann, Beate
    Stammler, Hans-Georg
    Hoge, Berthold
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (35) : 3904 - 3912
  • [9] Synthesis and chemistry of CF3C6F4OC6F4NH2 (RFNH2) and pseudohalogen derivatives;: crystal structures of RFX (X = COOH, COCl, CN, N3, NCS, NHCOCONHRF)
    Klapötke, TM
    Krumm, B
    Mayer, P
    Piotrowski, H
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (08): : 1983 - 1989
  • [10] Dihydrogen Activation with tBu3P/B(C6F5)3: A Chemically Competent Indirect Mechanism via in Situ-Generated p-tBu2P-C6F4-B(C6F5)2
    Marwitz, Adam J. V.
    Dutton, Jason L.
    Mercier, Lauren G.
    Piers, Warren E.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (26) : 10026 - 10029
12345