We argue that the large thermopower, magnetism, and superconductivity observed in NaxCoO2 share the same origin, namely, the peculiar shape of the a(1g) band. Superconductivity and magnetism arise from the local minimum structure of the band at the Gamma point, while the thermopower originates from the overall "pudding mold" shape of the band. Our study shows the importance of the band structure and the Fermi surface even in strongly correlated systems. (C) 2008 Elsevier Ltd. All rights reserved.
机构:
Nagoya Univ, EcoTopia Sci Inst, Nagoya, Aichi 4648603, Japan
Nagoya Univ, Dept Crystalline Mat Sci, Chikusa Ku, Nagoya, Aichi 4648603, JapanNagoya Univ, EcoTopia Sci Inst, Nagoya, Aichi 4648603, Japan
Takeuchi, Tsunehiro
Kuno, Syuhei
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Nagoya Univ, Dept Crystalline Mat Sci, Nagoya, Aichi 4648603, JapanNagoya Univ, EcoTopia Sci Inst, Nagoya, Aichi 4648603, Japan
Kuno, Syuhei
THERMOELECTRIC POWER GENERATION,
2008,
1044
: 51
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机构:
Univ Santiago de Compostela, Dept Chem Phys, Santiago De Compostela 15782, SpainUniv Santiago de Compostela, Dept Chem Phys, Santiago De Compostela 15782, Spain
Rivadulla, F
Bañobre-López, M
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机构:Univ Santiago de Compostela, Dept Chem Phys, Santiago De Compostela 15782, Spain
Bañobre-López, M
García-Hernández, M
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机构:Univ Santiago de Compostela, Dept Chem Phys, Santiago De Compostela 15782, Spain
García-Hernández, M
López-Quintela, MA
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机构:Univ Santiago de Compostela, Dept Chem Phys, Santiago De Compostela 15782, Spain
López-Quintela, MA
Rivas, J
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机构:Univ Santiago de Compostela, Dept Chem Phys, Santiago De Compostela 15782, Spain