Distinctly Different Reactivities of Two Similar Polyoxoniobates with Hydrogen Peroxide

被引：64

作者：

Ohlin, C. Andre ^{[1
]}

Villa, Eric M. ^{[1
]}

Fettinger, James C. ^{[1
]}

Casey, William H. ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem & Geol, Davis, CA 95616 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 43期

基金：

美国国家科学基金会;

关键词：

cluster compounds; kinetics; niobium; peroxides;

D O I：

10.1002/anie.200803688

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Peroxoniobate species are found whenever niobium oxides are employed as photocatalysts or used to sequester radionuclides. The reactions of [Nb6O19]8- and [Nb10O 28]6- with hydrogen peroxide each behave differently, and the first example of a peroxopolyoxoniobate species, [N(CH3) 4]5[H3Nb6O13(O (I)2)6]·9.5 H2O, was structurally characterized (see picture; Nb gray, O red, H white). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8251 / 8254

页数：4

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