Electrochemical Determination of Pentachlorophenol Using a Glassy Carbon Electrode Modified with a Film of CuS Nanocomposite-Chitosan

被引：13
|
作者：
Zou, Jing [1 ]
Ma, Jinai [1 ]
Zhang, Yuanxiao [1 ]
Li, Lu [1 ]
Jiang, Jizhou [2 ]
Chen, Jinfang [1 ]
机构：
[1] Wuhan Inst Technol, Sch Chem Engn & Pharm, Key Lab Green Chem Proc, Minist Educ, Wuhan 430073, Peoples R China
[2] Huazhong Univ Sci & Technol, Coll Chem & Chem Engn, Wuhan 430074, Peoples R China
来源：
ANALYTICAL LETTERS | 2013年 / 46卷 / 07期
关键词：
CuS nanocomposite; Cyclic voltammetry; Modified electrode; Pentachlorophenol; COPPER SULFIDE; NANOTUBES; WATER; CHLOROPHENOLS; HPLC; WOOD;
D O I：
10.1080/00032719.2012.749483
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A new electrochemical sensor was fabricated by modifying the glass carbon electrode surface with CuS nanocomposites and chitosan for the determination of pentachlorophenol. CuS nanocomposites obtained by a solvothermal method were composed primarily of CuS with hexagonal phase and Cu2Cl(OH)3 with a tetragonal phase. The results indicated that CuS nanocomposites possessed good electrochemical activity. After optimizing the experimental conditions, the linear dependence of current vs. pentachlorophenol concentration was reached in a range from 1.88x1067.50x105mol/L pentachlorophenol, and the detection limit was 6.25x107mol/L. The electrode displayed a high degree of stability and reproducibility. A new, simple, rapid, and highly sensitive electrochemical detection method of pentachlorophenol was established.
引用
收藏
页码：1108 / 1116
页数：9
相关论文
共 50 条
  • [21] Electrochemical determination of ajmalicine using glassy carbon electrode modified with gold nanoparticles
    Mehmeti, Eda
    Stankovic, Dalibor M.
    Chaiyo, Sudkate
    Svorc, L'ubomir
    Ortner, Astrid
    Kalcher, Kurt
    MONATSHEFTE FUR CHEMIE, 2016, 147 (07): : 1161 - 1166
  • [22] A glassy carbon electrode modified with carbon nanoonions for electrochemical determination of fentanyl
    Sohouli, Esmail
    Keihan, Amir Homayoun
    Shahdost-fard, Faezeh
    Naghian, Ebrahim
    Plonska-Brzezinska, Marta E.
    Rahimi-Nasrabadi, Mehdi
    Ahmadi, Farhad
    MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2020, 110
  • [23] Fabrication of an electrochemical immunosensor based on a gold-hydroxyapatite nanocomposite-chitosan film
    Shen, Guangyu
    Cai, Chenbo
    Yang, Jifeng
    ELECTROCHIMICA ACTA, 2011, 56 (24) : 8272 - 8277
  • [24] Electrochemical determination of dopamine using a glassy carbon electrode modified with a nanocomposite consisting of nanoporous platinum-yttrium and graphene
    Chen, Dandan
    Tian, Chunhuan
    Li, Xiangyi
    Li, Zihan
    Han, Zhida
    Zhai, Chun
    Quan, Ying
    Cui, Rongjing
    Zhang, Genhua
    MICROCHIMICA ACTA, 2018, 185 (02)
  • [25] Electrochemical determination of quercetin using glassy carbon electrode modified with WS2/GdCoO3 nanocomposite
    Mariyappan, Vinitha
    Karuppusamy, Naveen
    Chen, Shen-Ming
    Raja, Paulsamy
    Ramachandran, Rasu
    MICROCHIMICA ACTA, 2022, 189 (03)
  • [26] Electrochemical determination of dopamine using a glassy carbon electrode modified with a nanocomposite consisting of nanoporous platinum-yttrium and graphene
    Dandan Chen
    Chunhuan Tian
    Xiangyi Li
    Zihan Li
    Zhida Han
    Chun Zhai
    Ying Quan
    Rongjing Cui
    Genhua Zhang
    Microchimica Acta, 2018, 185
  • [27] Electrochemical determination of quercetin using glassy carbon electrode modified with WS2/GdCoO3 nanocomposite
    Vinitha Mariyappan
    Naveen Karuppusamy
    Shen-Ming Chen
    Paulsamy Raja
    Rasu Ramachandran
    Microchimica Acta, 2022, 189
  • [28] Simultaneous electrochemical determination of levodopa and piroxicam using a glassy carbon electrode modified with a ZnO-Pd/CNT nanocomposite
    Karimi-Maleh, Hassan
    Sheikhshoaie, Iran
    Samadzadeh, Ali
    RSC ADVANCES, 2018, 8 (47) : 26707 - 26712
  • [29] VOLTAMMETRIC DETERMINATION OF PENTACHLOROPHENOL AT A GLASSY-CARBON ELECTRODE
    GUIJARRO, EC
    YANEZSEDENO, P
    CARRAZON, JMP
    DIEZ, LMP
    ANALYST, 1988, 113 (04) : 625 - 627
  • [30] Study and Electrochemical Determination of Tyrosine at Graphene Nanosheets Composite Film Modified Glassy Carbon Electrode
    Behpour, M.
    Masoum, S.
    Meshki, M.
    JOURNAL OF NANOSTRUCTURES, 2013, 3 (02) : 243 - 251
12345