Vapor-Liquid Equilibrium Measurements for a Tetrafluoromethane plus Propane System over a Temperature Range from (142.96 to 293.23) K

被引:3
作者
Liu, Yanni [1 ,2 ]
Guo, Kaihua [1 ]
Lu, Laiyun [1 ]
机构
[1] Sun Yat Sen Univ, Sch Engn, Guangzhou 510275, Guangdong, Peoples R China
[2] Guangzhou Univ, Sch Civil Engn, Guangzhou 510006, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
EQUATION-OF-STATE; LIQUEFIED NATURAL-GAS; PHASE-EQUILIBRIA; VLE MEASUREMENTS; MIXING RULES; R-290; SYSTEM; COLD ENERGY; PRESSURES; MPA; MIXTURES;
D O I
10.1021/je300806e
中图分类号
O414.1 [热力学];
学科分类号
摘要
The isothermal vapor-liquid equilibrium (VLE) for tetrafluoromethane (CF4) + propane (C3H8) system was measured and P, T, and y data were collected at temperatures of (142.96, 163.07, 183.10, 203.26, 223.17, 243.12, 263.15, 283.01, and 293.23) K. A vapor recirculation method was employed to drive the mixing of the two components in the system and to quicken the equilibrium process. The experimental results were correlated with Peng-Robinson equation of state and the van der Waals two-parameters mixing rule. The mean deviations between the correlated and measured vapor compositions were found to be satisfactory within 0.01 and the data showed a good accuracy and consistency.
引用
收藏
页码:3611 / 3616
页数:6
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