Preparation of graphite oxide (GO) and the thermal stability of silicone rubber/GO nanocomposites

被引:137
作者
Wang, Xinlong [1 ]
Dou, Wangqi [1 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
关键词
Graphite oxide; Silicone rubber; Nanocomposite; Thermal stability; MECHANICAL-PROPERTIES;
D O I
10.1016/j.tca.2011.11.016
中图分类号
O414.1 [热力学];
学科分类号
摘要
Graphite oxide was synthesized by the oxidation of expanded graphite via a modified Hummers approach. The structure of graphite oxide was evaluated by TEM. XRD, Raman and FTIR. It was found that the structure of expanded graphite can be easily and remarkably disordered by oxidation. Silicone rubber/GO nanocomposites were prepared via a solution intercalation method. The structure of the nanocomposites was studied by XRD. The thermal behavior of the nanocomposites was characterized by TGA and the results showed that the addition of graphite oxide is beneficial to improve the thermal stability of the nanocomposites at high temperature. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:25 / 28
页数:4
相关论文
共 26 条
[1]   Can nanoparticles really enhance thermal stability of polymers? Part II: An overview on thermal decomposition of polycondensation polymers [J].
Bikiaris, D. .
THERMOCHIMICA ACTA, 2011, 523 (1-2) :25-45
[2]   Dye Adsorption on Layered Graphite Oxide [J].
Bradder, Philip ;
Ling, Sie King ;
Wang, Shaobin ;
Liu, Shaomin .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (01) :138-141
[3]   Piezoresistive behavior study on finger-sensing silicone rubber/graphite nanosheet nanocomposites [J].
Chen, Ling ;
Chen, Guohua ;
Lu, Liang .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (06) :898-904
[4]   Monolayer graphene from graphite oxide [J].
Dideykin, A. ;
Aleksenskiy, A. E. ;
Kirilenko, D. ;
Brunkov, P. ;
Goncharov, V. ;
Baidakova, M. ;
Sakseev, D. ;
Vul', A. Ya. .
DIAMOND AND RELATED MATERIALS, 2011, 20 (02) :105-108
[5]   The chemistry of graphene oxide [J].
Dreyer, Daniel R. ;
Park, Sungjin ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240
[6]   Mechanical properties, fire performance and thermal stability of magnesium hydroxide sulfate hydrate whiskers flame retardant silicone rubber [J].
Fang, Shoulin ;
Hu, Yuan ;
Song, Lei ;
Zhan, Jing ;
He, Qingliang .
JOURNAL OF MATERIALS SCIENCE, 2008, 43 (03) :1057-1062
[7]   Cellulose/graphite oxide composite films with improved mechanical properties over a wide range of temperature [J].
Han, Donglin ;
Yan, Lifeng ;
Chen, Wufeng ;
Li, Wan ;
Bangal, P. R. .
CARBOHYDRATE POLYMERS, 2011, 83 (02) :966-972
[8]   Characterization and electrical properties of conductive polymer/colloidal graphite oxide nanocomposites [J].
Han, Yongqin ;
Lu, Yun .
COMPOSITES SCIENCE AND TECHNOLOGY, 2009, 69 (7-8) :1231-1237
[9]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[10]   Thermal stability and ablation properties of silicone rubber composites [J].
Kim, Eung Soo ;
Kim, Eun Jeong ;
Shim, Jea Hun ;
Yoon, Jin-San .
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 110 (02) :1263-1270