Synthesis and Structure of 1-Substituted Semithioglycolurils

被引：9
作者：
Baranov, Vladimir V. [1 ]
Galochkin, Anton A. [1 ,2 ]
Nelyubina, Yulia V. [3 ]
Kravchenko, Angelina N. [1 ,4 ]
Makhova, Nina N. [1 ]
机构：
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prosp, Moscow 119991, Russia
[2] DI Mendeleev Univ Chem Technol Russia, 9 Miusskaya Sq, Moscow 125047, Russia
[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Vavilova St, Moscow 119991, Russia
[4] Plekhanov Russian Univ Econ, Stremyanny Lane 36, Moscow 117997, Russia
来源：
SYNTHESIS-STUTTGART | 2020年 / 52卷 / 17期
关键词：
semithioglycolurils; cyclocondensation; heterocycles; urea derivatives; thiourea derivatives; glyoxal; SUBSTITUTED UREAS; ALPHA-THIOUREIDOALKYLATION; UNEXPECTED FORMATION; THIOGLYCOLURILS; 4,5-DIHYDROXYIMIDAZOLIDIN-2-ONES; GLYCOLURILS; CONTRACTION; CYCLIZATION; ANALOGS;
D O I：
10.1055/s-0040-1707391
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Two methods for the synthesis of previously unavailable 1-substituted semithioglycolurils were developed. These methods consist of the cyclocondensation of 1-substituted ureas with 4,5-dihydroxy- or 4,5-dimethoxyimidazolidine-2-thione or glyoxal, followed by the reaction of the resulting 1-substituted 4,5-dihydroxyimidazolidine-2-ones with HSCN in a two-step one-pot procedure. Two of the desired semithioglycolurils were obtained as conglomerates.
引用
收藏
页码：2563 / 2571
页数：9
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