Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption

被引：49

作者：

Feldblyum, Jeremy I. ^{[1
]}

Wong-Foy, Antek G. ^{[1
]}

Matzger, Adam J. ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 79期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; PORE-SIZE DISTRIBUTIONS; HYDROGEN STORAGE; SURFACE-AREA; COORDINATION POLYMERS; PERMANENT POROSITY; H-2; BINDING; ADSORPTION; DESIGN; CO2;

D O I：

10.1039/c2cc34689c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and successful activation of IRMOF-8 (Zn4O(ndc)(3), ndc = naphthalene-2,6-dicarboxylate) is presented. Room temperature synthesis effectively suppresses interpenetration. Although conventional activation under reduced pressure leads to structural collapse, activation by flowing supercritical CO2 yields a guest-free material with a BET surface area of 4461 m(2) g(-1).

引用

页码：9828 / 9830

页数：3

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