One-electron redox processes of the Cu-II chelate of 3,8,12,17-tetraethyl-2,7,13,18-tetramethylbilin-1,19-dione

被引：3

作者：

Anglada, MC ^{[1
]}

Farrera, JA ^{[1
]}

Ribo, JM ^{[1
]}

机构：

[1] UNIV BARCELONA, DEPT ORGAN CHEM, E-08028 BARCELONA, SPAIN

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(96)02388-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In solution (CH2Cl2) one-electron redox process can be performed electrochemically on the ligand of the Cu-II chelate (1) of the title biliverdin. 1 shows an electronic triplet state configuration with one of the unpaired electrons in the ligand pi system. The one-electron oxidation product (1a) and the one electron reduction product (1b) correspond to the Cu-II chelates of the electron paired cation and anion respectively. (C) 1997, Published by Elsevier Science Ltd.

引用

页码：669 / 672

页数：4

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