Fluorine in liquid crystal design for display applications

被引:105
作者
Kirsch, Peer [1 ]
机构
[1] Liquid Crystals R&D Chem, Merck KGaA, D-64293 Darmstadt, Germany
关键词
Liquid crystals; Stereoelectronic effects; Conformation control; Electronegativity; Hypervalent sulfur fluorides; Fluorine effects; HYPERVALENT SULFUR FLUORIDES; TRANSITION-TEMPERATURES; DIELECTRIC ANISOTROPY; PHASE; TV;
D O I
10.1016/j.jfluchem.2015.01.007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Fluorine is an essential component of most liquid crystalline materials as they are used in LCD devices. The reasons for this are manifold: fluorination limits the coordination ability to cationic impurities and thus improves reliability of the LCD, it provides a custom-tailored molecular dipole moment with the right orientation, and it can stabilize certain conformations and rigidify flexible alkyl chains. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:29 / 36
页数:8
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