MCM-41-SO3H as an efficient reusable nano-ordered heterogeneous catalyst for the synthesis of divers 1-& 5-substituted 1H-tetrazoles

被引：17
作者：
Moghaddam, F. Matloubi [1 ]
Eslami, M. [1 ]
Ghadirian, N. [1 ]
机构：
[1] Sharif Univ Technol, Dept Chem, Lab Organ Synth & Nat Prod, POB 111559516, Tehran, Iran
来源：
SCIENTIA IRANICA | 2019年 / 26卷 / 03期
关键词：
Nano-ordered MCM-41-SO3H; 1-& 5-substituted tetrazoles; Click chemistry; 2+3] cycloaddition; ONE-POT SYNTHESIS; RECYCLABLE CATALYST; 3+2 CYCLOADDITION; FACILE SYNTHESIS; NANOPARTICLES; COMPLEX; 5-SUBSTITUTED-1H-TETRAZOLES; TETRAZOLES; NITRILES; CHLORIDE;
D O I：
10.24200/sci.2018.21088
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
An improved and efficient method for the synthesis of 1- & 5-substituted 1H-tetrazole derivatives was described in the presence of nano-ordered MCM-41-SO3H as an effective heterogeneous catalyst. This metal-free protocol, [2 + 3] cycloaddition of sodium azide to various nitriles or ethyl N-phenyl formimidate intermediate under mild reaction conditions, provides a wide range of 1H-tetrazoles in good to excellent yields. The catalyst was reused five times without significant loss of catalytic activity. (C) 2019 Sharif University of Technology. All rights reserved.
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收藏
页码：1463 / 1473
页数：11
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