Crystal and molecular structure of bromo(pi-allyl)cytidine palladium(II)

被引：8
|
作者：
Khan, BT [1 ]
Mohan, KM [1 ]
Khan, SRA [1 ]
Venkatasubramanian, K [1 ]
Satyanaryana, T [1 ]
机构：
[1] INDIAN INST CHEM TECHNOL,CRYSTALLOG LAB,HYDERABAD 500007,ANDHRA PRADESH,INDIA
来源：
POLYHEDRON | 1996年 / 15卷 / 01期
关键词：
D O I：
10.1016/0277-5387(95)00212-B
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal and molecular structure of bromo(pi-allyl)cytidine palladium(II) has been determined by X-ray diffraction analysis. In this complex, cytidine coordinates to palladium(II) through N-3. The pi-allyl moiety is coordinated as an eta(3)-ligand. The sugar fragment occurs as an envelope in the gauche-gauche conformation. The structure is supported by a network of hydrogen bonds.
引用
收藏
页码：63 / 67
页数：5
相关论文
共 50 条
  • [1] CRYSTAL STRUCTURE OF PI-ALLYL(TRIPHENYLPHOSPHINE)PALLADIUM-TRICHLOROTIN
    MASON, R
    WHIMP, PO
    JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (18): : 2709 - &
  • [2] PALLADIUM(II) POLYNUCLEAR PI-ALLYL COMPLEXES
    ROGACHEV, BG
    ROSHCHUP.OS
    KHIDEKEL, ML
    ASTAKHOV.AS
    IZVESTIYA AKADEMII NAUK SSSR-SERIYA KHIMICHESKAYA, 1972, (08): : 1855 - &
  • [3] MOLECULAR ASYMMETRY IN PI-ALLYL PALLADIUM COMPLEXES
    DECANDIA, F
    MAGLIO, G
    MUSCO, A
    PAIARO, G
    CHIMICA & L INDUSTRIA, 1968, 50 (08): : 930 - &
  • [4] FORMATION OF PI-ALLYL LIGAND FROM PYRYLIUM-SALTS - SYNTHESIS AND STRUCTURE OF NOVEL PI-ALLYL COMPLEXES OF PALLADIUM(II)
    UKHIN, LY
    ILIN, VI
    ORLOVA, ZI
    BOKII, NG
    STRUCHKOV, YT
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 113 (02) : 167 - 171
  • [5] STRUCTURE OF PI-ALLYL(TRIPHENYLPHOSPHINE)PALLADIUM-TRICHLOROTIN
    MASON, R
    ROBERTSO.GB
    WHIMP, PO
    WHITE, DA
    CHEMICAL COMMUNICATIONS, 1968, (24) : 1655 - &
  • [6] (PI-ALLYL)PALLADIUM COMPLEXES OF NORCAMPHENE - STRUCTURE AND REACTIVITY
    GODLESKI, SA
    GUNDLACH, KB
    HO, HY
    KEINAN, E
    FROLOW, F
    ORGANOMETALLICS, 1984, 3 (01) : 21 - 28
  • [7] PREPARATION AND REACTIONS OF (PI-ALLYL)PALLADIUM AND (PI-ALLYL)PLATINUM CARBONATE COMPLEXES
    OZAWA, F
    SON, TI
    EBINA, S
    OSAKADA, K
    YAMAMOTO, A
    ORGANOMETALLICS, 1992, 11 (01) : 171 - 176
  • [8] PI-ALLYL CATIONIC COMPLEXES OF PALLADIUM(II) WITH CLOSOBORATE ANION
    ZAKHAROVA, IA
    GAFT, YL
    KUZNETSOV, NT
    SALYN, YV
    LEITES, LA
    KURBAKOVA, AP
    KAGANSKY, MM
    INORGANICA CHIMICA ACTA-ARTICLES, 1981, 47 (02): : 181 - 186
  • [9] REACTION OF PHENYLHYDRAZONES WITH BIS(PI-ALLYL)-NICKEL AND BIS(PI-ALLYL)-PALLADIUM COMPLEXES
    BAKER, R
    NOBBS, MS
    ROBINSON, DT
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1978, (06): : 543 - 549
  • [10] PARAMAGNETIC PI-ALLYL COMPLEXES OF PALLADIUM
    MILAEVA, ER
    RUBEZHOV, AZ
    PROKOFEV, AI
    OKHLOBYSTIN, OY
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 193 (01) : 135 - 145
12345