Charging and discharging electrochemical supercapacitors in the presence of both parallel leakage process and electrochemical decomposition of solvent

被引：81

作者：

Ban, Shuai ^{[1
]}

Zhang, Jiujun ^{[1
]}

Zhang, Lei ^{[1
]}

Tsay, Ken ^{[1
]}

Song, Datong ^{[1
]}

Zou, Xinfu ^{[2
]}

机构：

[1] Natl Res Council Canada, Vancouver, BC V6T 1W5, Canada

[2] Univ Western Ontario, Dept Appl Math, London, ON N6A 5B7, Canada

来源：

ELECTROCHIMICA ACTA | 2013年 / 90卷

关键词：

Electrochemical supercapacitor; Charge and discharge; Parallel leakage; Self-discharging; Solvent decomposition; ORGANIC ELECTROLYTES; VOLTAGE; PORE;

D O I：

10.1016/j.electacta.2012.12.056

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Simple models for electrochemical supercapacitors are developed to describe the charge discharge behaviors in the presence of both voltage-independent parallel leakage process and electrochemical decomposition of solvent. The models are validated by experimental data collected using a symmetric two-electrode test cell with carbon powder as the electrode layer material and stainless steel as the current collector. (C) 2013 Published by Elsevier Ltd.

引用

页码：542 / 549

页数：8

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