STM manipulation of a subphthalocyanine double-wheel molecule on Au(111)

被引：14

作者：

Nickel, Anja ^{[1
,2
]}

Meyer, Joerg ^{[1
,2
]}

Ohmann, Robin ^{[1
,2
]}

de Rouville, Henri-Pierre Jacquot ^{[3
,4
]}

Rapenne, Gwenael ^{[3
,4
,5
]}

Ample, Francisco ^{[6
]}

Joachim, Christian ^{[3
,4
,6
]}

Cuniberti, Gianaurelio ^{[1
,2
,7
]}

Moresco, Francesca ^{[1
,2
]}

机构：

[1] Tech Univ Dresden, Inst Mat Sci, D-01062 Dresden, Germany

[2] Tech Univ Dresden, Max Bergmann Ctr Biomat, D-01062 Dresden, Germany

[3] CNRS, CEMES, F-31055 Toulouse, France

[4] MANA Satellite Ctr Elaborat Mat & Etud Struct, F-31055 Toulouse, France

[5] Univ Toulouse, UPS, F-31055 Toulouse, France

[6] ASTAR, IMRE, Singapore 117602, Singapore

[7] POSTECH, Div IT Convergence Engn, Pohang 790784, South Korea

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 2012年 / 24卷 / 40期

关键词：

SCANNING-TUNNELING-MICROSCOPY; ATOMIC-SCALE; SURFACE; MACHINES; ROTATION;

D O I：

10.1088/0953-8984/24/40/404001

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

A new class of double-wheel molecules is manipulated on a Au(111) surface by the tip of a scanning tunneling microscope (STM) at low temperature. The double-wheel molecule consists of two subphthalocyanine wheels connected by a central rotation carbon axis. Each of the subphthalocyanine wheels has a nitrogen tag to monitor its intramolecular rolling during an STM manipulation sequence. The position of the tag can be followed by STM, allowing us to distinguish between the different lateral movements of the molecule on the surface when manipulated by the STM tip.

引用

页数：6

共 23 条

[1] Recording the intramolecular deformation of a 4-legs molecule during its STM manipulation on a Cu(211) surface [J].

Alemani, M ;

Gross, L ;

Moresco, F ;

Rieder, KH ;

Wang, C ;

Bouju, X ;

Gourdon, A ;

Joachim, C .

CHEMICAL PHYSICS LETTERS, 2005, 402 (1-3) :180-185

[2] A semi-empirical study of polyacene molecules adsorbed on a Cu(110) surface [J].

Ample, F. ;

Joachim, C. .

SURFACE SCIENCE, 2006, 600 (16) :3243-3251

[3] Basic steps of lateral manipulation of single atoms and diatomic clusters with a scanning tunneling microscope tip [J].

Bartels, L ;

Meyer, G ;

Rieder, KH .

PHYSICAL REVIEW LETTERS, 1997, 79 (04) :697-700

[4] SCANNING TUNNELING MICROSCOPY OBSERVATIONS ON THE RECONSTRUCTED AU(111) SURFACE - ATOMIC-STRUCTURE, LONG-RANGE SUPERSTRUCTURE, ROTATIONAL DOMAINS, AND SURFACE-DEFECTS [J].

BARTH, JV ;

BRUNE, H ;

ERTL, G ;

BEHM, RJ .

PHYSICAL REVIEW B, 1990, 42 (15) :9307-9318

[5] Single-atom motion during a lateral STM manipulation [J].

Bouju, X ;

Joachim, C ;

Girard, C .

PHYSICAL REVIEW B, 1999, 59 (12) :R7845-R7848

[6] Synthesis and Reactivity of [Penta(4-halogenophenyl)cyclopentadienyl]-[hydrotris(indazolyl)borato]ruthenium(II) Complexes: Rotation-Induced Fosbury Flop in an Organometallic Molecular Turnstile [J].

Carella, Alexandre ;

Launay, Jean-Pierre ;

Poteau, Romuald ;

Rapenne, Gwenael .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (27) :8147-8156

[7] A rack-and-pinion device at the molecular scale [J].

Chiaravalloti, Franco ;

Gross, Leo ;

Rieder, Karl-Heinz ;

Stojkovic, Sladjana M. ;

Gourdon, Andre ;

Joachim, Christian ;

Moresco, Francesca .

NATURE MATERIALS, 2007, 6 (01) :30-33

[8] Synthesis and STM Imaging of Symmetric and Dissymmetric Ethynyl-Bridged Dimers of Boron-Subphthalocyanine Bowl-Shaped Nanowheels [J].

de Rouville, Henri-Pierre Jacquot ;

Garbage, Romain ;

Ample, Francisco ;

Nickel, Anja ;

Meyer, Joerg ;

Moresco, Francesca ;

Joachim, Christian ;

Rapenne, Gwenael .

CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (29) :8925-8928

[9] Rolling a single molecular wheel at the atomic scale [J].

Grill, L. ;

Rieder, K. -H. ;

Moresco, F. ;

Rapenne, G. ;

Stojkovic, S. ;

Bouju, X. ;

Joachim, C. .

NATURE NANOTECHNOLOGY, 2007, 2 (02) :95-98

[10] Imaging of a molecular wheelbarrow by scanning tunneling microscopy [J].

Grill, L ;

Rieder, KH ;

Moresco, F ;

Jimenez-Bueno, G ;

Wang, C ;

Rapenne, G ;

Joachim, C .

SURFACE SCIENCE, 2005, 584 (2-3) :L153-L158

← 1 2 3 →