Natural Gas to Fuels and Chemicals: Improved Methane Aromatization in an Oxygen-Permeable Membrane Reactor

被引：97

作者：

Cao, Zhengwen ^{[1
]}

Jiang, Heqing ^{[2
]}

Luo, Huixia ^{[1
,3
]}

Baumann, Stefan ^{[4
]}

Meulenberg, Wilhelm A. ^{[4
]}

Assmann, Jens ^{[5
]}

Mleczko, Leslaw ^{[5
]}

Liu, Yi ^{[1
]}

Caro, Juergen ^{[1
]}

机构：

[1] Leibniz Univ Hannover, Inst Phys Chem & Electrochem, D-30167 Hannover, Germany

[2] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China

[3] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

[4] Forschungszentrum Julich GmbH, Inst Energy & Climate Res, D-52425 Julich, Germany

[5] Bayer Technol Serv GmbH, BTS TD UP Chem Catalysis, D-51368 Leverkusen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 51期

关键词：

aromatic compounds; dehydroaromatization; membrane reactors; methane; oxygen-permeable membranes; NONOXIDATIVE ACTIVATION; CATALYTIC PERFORMANCE; HYDROGEN-PRODUCTION; WATER DISSOCIATION; CONVERSION; MO/HZSM-5; PEROVSKITE; DEHYDROAROMATIZATION; DEHYDROGENATION; REDUCTION;

D O I：

10.1002/anie.201307935

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Adding value with membranes: Improved methane aromatization was achieved by using an oxygen-permeable membrane. The resulting membrane reactor shows a superior methane conversion and a higher resistance towards catalyst deactivation. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：13794 / 13797

页数：4

共 48 条

[1]

[Anonymous], 2013, Angew. Chem.

[2] Hydrogen production by water dissociation using mixed conducting dense ceramic membranes [J].

Balachandran, U. ;

Lee, T. H. ;

Dorris, S. E. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (04) :451-456

[3] Ultrahigh oxygen permeation flux through supported Ba0.5Sr0.5Co0.8Fe0.2O3-δ membranes [J].

Baumann, S. ;

Serra, J. M. ;

Lobera, M. P. ;

Escolastico, S. ;

Schulze-Kueppers, F. ;

Meulenberg, W. A. .

JOURNAL OF MEMBRANE SCIENCE, 2011, 377 (1-2) :198-205

[4] Dense ceramic membranes for methane conversion [J].

Bouwmeester, HJM .

CATALYSIS TODAY, 2003, 82 (1-4) :141-150

[5] Simultaneous overcome of the equilibrium limitations in BSCF oxygen-permeable membrane reactors: Water splitting and methane coupling [J].

Cao, Zhengwen ;

Jiang, Heqing ;

Luo, Huixia ;

Baumann, Stefan ;

Meulenberg, Wilhelm A. ;

Voss, Hartwig ;

Caro, Juergen .

CATALYSIS TODAY, 2012, 193 (01) :2-7

[6] THE STUDY OF ETHANE DEHYDROGENATION IN A CATALYTIC MEMBRANE REACTOR [J].

CHAMPAGNIE, AM ;

TSOTSIS, TT ;

MINET, RG ;

WAGNER, E .

JOURNAL OF CATALYSIS, 1992, 134 (02) :713-730

[7] Conversion of methane to syngas by a membrane-based oxidation-reforming process [J].

Chen, CS ;

Feng, SJ ;

Ran, S ;

Zhu, DC ;

Liu, W ;

Bouwmeester, HJM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (42) :5196-5198

[8]

CHEN CS, 2003, ANGEW CHEM, V115, P5354

[9] Nonoxidative activation of methane [J].

Choudhary, TV ;

Aksoylu, E ;

Goodman, DW .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2003, 45 (01) :151-203

[10] Low-temperature nonoxidative activation of methane over H-galloaluminosilicate (MFI) zeolite [J].

Choudhary, VR ;

Kinage, AK ;

Choudhary, TV .

SCIENCE, 1997, 275 (5304) :1286-1288

← 1 2 3 4 5 →