Synthesis of N-Sulfonylamidated and Amidated Azobenzenes under Rhodium Catalysis

被引：34

作者：

Han, Sangil ^{[1
]}

Mishra, Neeraj Kumar ^{[1
]}

Sharma, Satyasheel ^{[1
]}

Park, Jihye ^{[1
]}

Choi, Miji ^{[1
]}

Lee, Seok-Yong ^{[1
]}

Oh, Joa Sub ^{[2
]}

Jung, Young Hoon ^{[1
]}

Kim, In Su ^{[1
]}

机构：

[1] Sungkyunkwan Univ, Sch Pharm, Suwon 440746, South Korea

[2] Dankook Univ, Coll Pharm, Cheonan 330714, South Korea

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 80卷 / 16期

基金：

新加坡国家研究基金会;

关键词：

C-H BOND; AROMATIC AZO-COMPOUNDS; DECARBOXYLATIVE ORTHO-ACYLATION; CYCLIZATION DIRECT SYNTHESIS; ALPHA-OXOCARBOXYLIC ACIDS; INTRAMOLECULAR CYCLIZATION; DIRECT FUNCTIONALIZATION; CONVERGENT SYNTHESIS; OXIDATIVE ACYLATION; BRANCHED AMINES;

D O I：

10.1021/acs.joc.5b01149

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rhodium(III)-catalyzed ortho-C-H amidation of azobenzenes with arylsulfonyl and aryl and alkyl isocyanates is described. The N-sulfonyl amidation reaction using arylsulfonyl isocyanates is first reported in the C-H activation strategy. These transformations provide the facile and efficient construction of a range of amide moieties into azob enzenes.

引用

收藏

页码：8026 / 8035

页数：10

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