A new (4,6)-connected Cu(I) coordination polymer based on rare tetranuclear [Cu4I2] clusters: Synthesis, crystal structure, luminescent and photocatalytic properties

被引：3

作者：

Cui, Li-Jing ^{[1
]}

Liu, Chun-Yan ^{[2
]}

Bian, Ming ^{[2
]}

Yu, Li-Jun ^{[2
]}

机构：

[1] Guangdong Food & Drug Vocat Coll, Guangzhou, Guangdong, Peoples R China

[2] Inner Mongolia Univ Nationalities, Med Chem & Pharmacol Inst, Tongliao, Inner Mongolia, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2018年 / 1155卷

关键词：

Cu(l) compound; Solvothermal synthesis; Luminescence; Photocatalytic activity; ACTIVATED DELAYED FLUORESCENCE; EFFICIENT CUPROUS COMPLEXES; IMIDAZOLATE FRAMEWORKS; OLEDS;

D O I：

10.1016/j.molstruc.2017.10.108

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new Cu(I) coordination polymer, namely [Cu5I3(L)(2)](n) (1 HL = 3-(4-pyridy1)-5-(3-pyridy1)-1,2,4-triazolyl), was solvothermally synthesized using Cu!, HL and NaI as the starting materials. Single crystal X-ray structural analysis shows that compound 1 features a (4, 6)-connected 3D framework employing rare tetranuclear [Cu4I2] clusters as building subunits. It exhibits intense metal-to-ligand luminescence and excellent photocatalytic activity on degradation of methylene blue (MB). (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：7 / 10

页数：4

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