Dielectric relaxation of propan-1-ol with chlorobenzene, 1,2-dichloroethane, and dimethylene chloride at (288, 298, 308, and 318) K using time-domain reflectometry technique

被引:19
作者
Pawar, V. P. [1 ]
机构
[1] Maharashtra Udayagiri Mahavidyalaya, Dept Phys & Elect, Udgir 413517, Maharashtra, India
关键词
D O I
10.1021/je0503397
中图分类号
O414.1 [热力学];
学科分类号
摘要
The values of complex permittivity of molecules containing chlorine with propan-1-ol binary mixtures have been determined over the frequency range of (0.1 to 20) GHz, at temperatures of ( 288, 298, 308, and 318) K, using the time-domain reflectometry (TDR) method for 11 molalities of each molecule containing chlorine with propan-1-ol system. The dielectric relaxation in these systems can be described by a single relaxation time using the Havriliak and Negami model. The static dielectric constant (epsilon(0)) and relaxation time (tau) have been obtained by fitting experimental data with the Havriliak-Negami equation.
引用
收藏
页码:882 / 885
页数:4
相关论文
共 26 条
[1]   Complex permittivity spectra of binary pyridine-amide mixtures using time-domain reflectometry [J].
Ahire, S ;
Chaudhari, A ;
Lokhande, M ;
Mehrotra, SC .
JOURNAL OF SOLUTION CHEMISTRY, 1998, 27 (11) :993-1008
[2]  
*ALDR CHEM CO, 1990, CAT HDB FIN CHEM
[3]  
Bevington R., 1969, DATA REDUCTION ERROR
[4]   Temperature dependent dielectric relaxation study of Tetrahydrofuran in Methanol and Ethanol at microwave frequency using Time Domain Technique. [J].
Chaudhari, A ;
Khirade, P ;
Singh, R ;
Helambe, SN ;
Narain, NK ;
Mehrotra, SC .
JOURNAL OF MOLECULAR LIQUIDS, 1999, 82 (03) :245-253
[5]   Dispersion and absorption in dielectrics I. Alternating current characteristics [J].
Cole, KS ;
Cole, RH .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (04) :341-351
[6]   TIME DOMAIN REFLECTION METHODS FOR DIELECTRIC MEASUREMENTS TO GHZ [J].
COLE, RH ;
BERBERIAN, JG ;
MASHIMO, S ;
CHRYSSIKOS, G ;
BURNS, A ;
TOMBARI, E .
JOURNAL OF APPLIED PHYSICS, 1989, 66 (02) :793-802
[7]   DIELECTRIC RELAXATION IN GLYCERINE [J].
DAVIDSON, DW ;
COLE, RH .
JOURNAL OF CHEMICAL PHYSICS, 1950, 18 (10) :1417-1417
[8]  
Frolhich H., 1949, THEORY DIELECTRICS
[9]  
HAVRILIAK S, 1966, J POLYM SCI POL SYM, P99
[10]   A COMPARATIVE DIELECTRIC-RELAXATION STUDY BETWEEN HYDROGEN-BONDED AND NON-HYDROGEN-BONDED LIQUIDS - NITRILES VS ALCOHOLS [J].
HELAMBE, SN ;
LOKHANDE, MP ;
KUMBHARKHANE, AC ;
MEHROTRA, SC .
PRAMANA-JOURNAL OF PHYSICS, 1995, 45 (01) :19-24