Manganese-Mediated C-C Bond Formation via C-H Activation: From Stoichiometry to Catalysis

被引：168
|
作者：
Wang, Congyang [1 ]
机构：
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China
来源：
SYNLETT | 2013年 / 24卷 / 13期
基金：
中国国家自然科学基金;
关键词：
manganese; C-H activation; catalysis; C-C bond formation; arenes; ORTHO-MANGANATED ARENES; CARBON-CARBON BONDS; CYCLOMANGANATED CHALCONES; 1,3-DICARBONYL COMPOUNDS; ORTHO-FUNCTIONALIZATION; COUPLING REACTIONS; CRYSTAL-STRUCTURE; ARYL-KETONES; COMPLEXES; INSERTION;
D O I：
10.1055/s-0033-1339299
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
C-H activation is an emerging powerful strategy to functionalize organic molecules alternative to traditional synthetic tools. Despite being cheap and abundant in the earth's crust, manganese is far less studied within the realm of C-H activation, in particular for C-C bond formation, compared to 'noble' transition metals. Herein, we provide a state-of-the-art review on Mn-mediated C-C bond-forming reactions, both stoichiometric and catalytic, via C-H bond activation.
引用
收藏
页码：1606 / 1613
页数：8
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