β-diketonates of cyclopalladated arylazonaphthalenes:: synthesis, characterization and redox activity

被引：3

作者：

Bhawmick, Rupa ^{[1
]}

Das, Purak ^{[1
]}

Acharya, Suvra ^{[1
]}

Biswas, Achintesh Narayan ^{[1
]}

Bandyopadhyay, Pinaki ^{[1
]}

机构：

[1] Univ N Bengal, Dept Chem, Darjeeling 734013, India

来源：

TRANSITION METAL CHEMISTRY | 2006年 / 31卷 / 04期

关键词：

D O I：

10.1007/s11243-006-0024-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of monomeric mixed species of the type [PdLK] (L = cyclopalladated arylazonaphthalenes) have been achieved by splitting the halogeno-bridge in [Pd2L2Cl2] by beta-diketones (HK). The compounds have been characterized on the basis of spectral (IR, UV-VIS, FAB mass, H-1 and C-13{H-1}NMR) and elemental analysis data. Some of the [PdLK] cyclometallates occur as isomeric mixtures whose composition have been established by H-1-NMR data. Electron transfer properties of the cyclopalladates in DMF have been thoroughly examined using cyclic voltammetry.

引用

页码：495 / 499

页数：5

共 51 条

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