A novel cobalt metal-organic framework with an anionic 3D network built up from two interconnected NbO subnets

被引：12
|
作者：
Livage, Carine [1 ]
Guillou, Nathalie [1 ]
Castiglione, Andrea [1 ]
Marrot, Jerome [1 ]
Frigoli, Michel [1 ]
Millange, Franck [1 ]
机构：
[1] Univ Versailles St Quentin En Yvelines, Inst Lavoisier, UMR CNRS 8180, F-78035 Versailles, France
来源：
MICROPOROUS AND MESOPOROUS MATERIALS | 2012年 / 157卷
关键词：
Carboxylate ligand; Metal-organic frameworks; NbO topology; Cobalt(II); Microporous materials; SINGLE-CRYSTAL; COORDINATION POLYMER; REDOX; CHEMISTRY; TRANSFORMATION; TOPOLOGY; GEOMETRY; DESIGN;
D O I：
10.1016/j.micromeso.2011.10.001
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The solvothermal reaction of cobalt chloride and 4,4',4 ''-nitrilotrisbenzoic acid (H3NTB) in N,N'-dimethylformamide (DMF) affords a new three-dimensional Co-NTB compound with an empirical formula of HDMA(2)[Co-5(NTB)(4)(H2O)(3)(DMA)]center dot 7DMF (HDMA(+), dimethylammonium). Its anionic network is built up from two connected NbO subnets and presents large hexagonal and small triangular channels containing the cations and the solvent molecules. (C) 2011 Elsevier Inc. All rights reserved.
引用
收藏
页码：37 / 41
页数：5
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