Study of malachite green adsorption by organically modified clay using a batch method

被引:116
作者
Arellano-Cardenas, Sofia [1 ]
Lopez-Cortez, Socorro [1 ]
Cornejo-Mazon, Maribel [1 ]
Carlos Mares-Gutierrez, Juan [1 ]
机构
[1] Escuela Nacl Ciencias Biol IPN, Dept Biofis, Mexico City 11340, DF, Mexico
关键词
Adsorption; Malachite green; Dye; Organoclay; Modified clay; TEXTILE DYE; CATIONIC SURFACTANT; AQUEOUS-SOLUTIONS; BENTONITE; REMOVAL; EQUILIBRIUM; PHENOL; FISH;
D O I
10.1016/j.apsusc.2013.04.097
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The adsorption of toxic dye malachite green from aqueous effluents by organically modified clay was studied in a batch system. The organoclay (OC) used was prepared by the intercalation of cationic surfactant hexadecyltrimethylammonium bromide in a Mexican montmorillonite. The effects of initial dye concentration, temperature, pH, and contact time were investigated. The OC showed a high dye removal (99.6%) from an initial dye concentration of 60 mg L-1 at pH 6 and 25 degrees C. The adsorption capacity was independent of pH and increased with the temperature. Equilibrium data were well fitted by Langmuir adsorption model. The rate of sorption was adjusted to a pseudo second-order kinetic model. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:74 / 78
页数:5
相关论文
共 28 条
[1]   Adsorption studies of hazardous malachite green onto treated ginger waste [J].
Ahmad, Rais ;
Kumar, Rajeev .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2010, 91 (04) :1032-1038
[2]   Adsorptive removal of tannin from aqueous solutions by cationic surfactant-modified bentonite clay [J].
Anirudhan, T. S. ;
Ramachandran, M. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 299 (01) :116-124
[3]   Preparation of a porous clay heterostructure and study of its adsorption capacity of phenol and chlorinated phenols from aqueous solutions [J].
Arellano-Cardenas, Sofia ;
Gallardo-Velazquez, Tzayhri ;
Osorio-Revilla, Guillermo ;
Lopez-Cortez, Ma. del Socorro .
WATER ENVIRONMENT RESEARCH, 2008, 80 (01) :60-67
[4]   SORPTION OF NARINGIN FROM AQUEOUS SOLUTION BY MODIFIED CLAY [J].
Arellano-Cardenas, Sofia ;
Gallardo-Velazquez, Tzayhri ;
Poumian-Gamboa, Gloria V. ;
Osorio-Revilla, Guillermo ;
Lopez-Cortez, Socorro ;
Rivera-Espinoza, Yadira .
CLAYS AND CLAY MINERALS, 2012, 60 (02) :153-161
[5]   Malachite green residues in farmed fish in Croatia [J].
Bilandzic, Nina ;
Varenina, Ivana ;
Kolanovic, Bozica Solomun ;
Oraic, Drazen ;
Zrncic, Snjezana .
FOOD CONTROL, 2012, 26 (02) :393-396
[6]   Thermal treatment of organoclays: Effect on the aqueous sorption of nitrobenzene on n-hexadecyltrimethyl ammonium montmorillonite [J].
Borisover, Mikhail ;
Bukhanovsky, Nadezhda ;
Lapides, Isaak ;
Yariv, Shmuel .
APPLIED SURFACE SCIENCE, 2010, 256 (17) :5539-5544
[7]   Adsorption of malachite green onto bentonite:: Equilibrium and kinetic studies and process design [J].
Bulut, Emrah ;
Oezacar, Mahmut ;
Sengil, I. Ayhan .
MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 115 (03) :234-246
[8]   Deflocculant effects on the surface properties of kaolinite investigated through malachite green adsorption [J].
Castellini, Elena ;
Andreoli, Roberto ;
Malavasi, Gianluca ;
Pedone, Alfonso .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 329 (1-2) :31-37
[9]   Modeling the adsorption of textile dye on organoclay using an artificial neural network [J].
Elemen, Seniha ;
Kumbasar, Emriye Perrin Akcakoca ;
Yapar, Saadet .
DYES AND PIGMENTS, 2012, 95 (01) :102-111
[10]   STUDIES IN ADSORPTION .11. A SYSTEM OF CLASSIFICATION OF SOLUTION ADSORPTION ISOTHERMS, AND ITS USE IN DIAGNOSIS OF ADSORPTION MECHANISMS AND IN MEASUREMENT OF SPECIFIC SURFACE AREAS OF SOLIDS [J].
GILES, CH ;
MACEWAN, TH ;
NAKHWA, SN ;
SMITH, D .
JOURNAL OF THE CHEMICAL SOCIETY, 1960, (OCT) :3973-3993