A newly Synthesis and characterization of metal complexes of 3-(N-phenyl) thiourea-pentanone-2 as ligand

被引:3
作者
Mishra, A. [1 ,2 ]
Ninama, S. [1 ,2 ]
Sharma, P.
Soni, N. [1 ,2 ]
Awate, R. [1 ,2 ]
机构
[1] Devi Ahilya Univ, Sch Phys, Indore 452001, Madhya Pradesh, India
[2] Devi Ahilya Univ, Sch Chem Sci, Indore 452001, Madhya Pradesh, India
来源
INTERNATIONAL CONFERENCE ON RECENT TRENDS IN PHYSICS (ICRTP 2012) | 2012年 / 365卷
关键词
D O I
10.1088/1742-6596/365/1/012039
中图分类号
O59 [应用物理学];
学科分类号
摘要
Present communication deals with the synthesis of copper and cobalt complexes derived from 3-(N-phenyl) thiourea-pentanone-2 as the ligand. Structure of all the compounds was characterized by elemental, XRD, FTIR, UV-VIS, SEM and (HNMR)-H-1 spectroanalytical studies. The X-ray diffraction studies indicate that 3-(N-phenyl) thiourea-pentanone-2 and their complexation with copper and cobalt metals are crystalline in nature. The FTIR spectroscopic data were used to assign the characteristic vibrational frequencies of various groups present in the compounds. Scanning electron Micrograms were used to assign the morphology and particle size of the compounds.
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页数:5
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共 10 条
[1]   Crystal structure and thermal behaviour of copper(II) and zinc(II) complexes with N-pyrrolidine-N′-(2-chloro-benzoyl)thiourea [J].
Arslan, H ;
Flörke, U ;
Külcü, N ;
Emen, MF .
JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (02) :223-228
[2]   Platinum thiosemicarbazide and thiourea complexes:: the crystal structure of [PtCl(dppe){SC(NHMe)NHNMe2-S}](PF6) and the influence of intramolecular hydrogen bonding on ligand co-ordination mode [J].
Burrows, AD ;
Coleman, MD ;
Mahon, MF .
POLYHEDRON, 1999, 18 (20) :2665-2671
[3]  
CULLITY BD, 1978, ELEMENTS XRAY DIFFRA, pCH5
[4]   Liquid-liquid extraction of palladium(II) and gold(III) with N-benzoyl-N′,N′-diethylthiourea and the synthesis of a palladium benzoylthiourea complex [J].
Domínguez, M ;
Anticó, E ;
Beyer, L ;
Aguirre, A ;
García-Granda, S ;
Salvadó, V .
POLYHEDRON, 2002, 21 (14-15) :1429-1437
[5]  
Goldstein J., 2003, Scanning electron microscopy and X-ray microanalysis, V3rd, P21, DOI [DOI 10.1007/978-1-4615-0215-9_2, DOI 10.1007/978-1-4615-0215-9]
[6]   INVESTIGATIONS ON TRIALLYLTHIOUREA MERCURY BROMIDE (ATMB) CRYSTAL-GROWTH [J].
HOU, WB ;
XU, D ;
YUAN, DR ;
LIU, MG ;
ZHANG, N ;
TAO, XT ;
SUN, SY ;
JIANG, MH .
CRYSTAL RESEARCH AND TECHNOLOGY, 1994, 29 (07) :939-944
[7]  
K Nakamoto, 2009, INFRARED RAMAN SPECT, P333
[8]  
MADAN VK, 1991, J INDIAN CHEM SOC, V68, P471
[9]  
W Hederson, 2002, INORG CHIM ACTA, V338, P210
[10]  
Yesilkaynak T., 2010, Eur. J. Chem., V1, P1