Iron-mediated direct arylation with arylboronic acids through an aryl radical transfer pathway

被引：117

作者：

Wang, Jian ^{[1
]}

Wang, Shan ^{[1
]}

Wang, Gao ^{[1
]}

Zhang, Ji ^{[1
]}

Yu, Xiao-Qi ^{[1
]}

机构：

[1] Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Coll Chem, Chengdu 610064, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 96期

基金：

美国国家科学基金会;

关键词：

C-H ARYLATION; CATALYZED DIRECT ARYLATION; CROSS-COUPLING REACTIONS; MANGANESE(III) ACETATE; BOND FORMATION; OXIDATION; SUBSTITUTIONS; HETEROCYCLES; BENZENE; BIARYLS;

D O I：

10.1039/c2cc35468c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel iron-mediated direct C-H arylation of quinones and pyridine analogues with arylboronic acids has been developed using dichloromethane and water as solvents at ambient temperature. FeS is employed and serves as an efficient catalyst. A detailed reaction mechanism is speculated and expounded.

引用

页码：11769 / 11771

页数：3

共 58 条

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