Iron-mediated direct arylation with arylboronic acids through an aryl radical transfer pathway

被引：117
作者：
Wang, Jian [1 ]
Wang, Shan [1 ]
Wang, Gao [1 ]
Zhang, Ji [1 ]
Yu, Xiao-Qi [1 ]
机构：
[1] Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Coll Chem, Chengdu 610064, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 96期
基金：
美国国家科学基金会;
关键词：
C-H ARYLATION; CATALYZED DIRECT ARYLATION; CROSS-COUPLING REACTIONS; MANGANESE(III) ACETATE; BOND FORMATION; OXIDATION; SUBSTITUTIONS; HETEROCYCLES; BENZENE; BIARYLS;
D O I：
10.1039/c2cc35468c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel iron-mediated direct C-H arylation of quinones and pyridine analogues with arylboronic acids has been developed using dichloromethane and water as solvents at ambient temperature. FeS is employed and serves as an efficient catalyst. A detailed reaction mechanism is speculated and expounded.
引用
收藏
页码：11769 / 11771
页数：3
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