Pincer-type bis(carbene)-derived complexes of nickel(II): Synthesis, structure, and catalytic activity

被引：88

作者：

Inamoto, Kiyofumi ^{[1
]}

Kuroda, Jun-ichi ^{[1
]}

Kwon, Eunsang ^{[2
]}

Hiroya, Kou ^{[1
]}

Doi, Takayuki ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Aoba Ku, Sendai, Miyagi 9808578, Japan

[2] Tohoku Univ, Grad Sch Sci, Res & Analyt Ctr Giant Mol, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 03期

基金：

日本学术振兴会;

关键词：

Pincer complex; Nickel; N-heterocyclic carbene; Suzuki-Miyaura coupling; N-HETEROCYCLIC CARBENE; COUPLING REACTIONS; PCP-PINCER; PALLADIUM COMPLEXES; DICARBENE COMPLEXES; METAL-COMPLEXES; ARYL CHLORIDES; X-RAY; COORDINATION; LIGANDS;

D O I：

10.1016/j.jorganchem.2008.11.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Air- and moisture-stable NHC (N-heterocyclic carbene)-derived CNC-type pincer complexes of nickel(II) 4a-d were successfully synthesized, and their structures were fully characterized using X-ray crystallography and analytical and spectroscopic methods. These complexes exhibit a high catalytic activity for the Suzuki-Miyaura coupling reaction of aryl bromides and chlorides with aryl- and alkenylboronic acids, providing an array of biphenyls and stilbenes generally in high yields. (C) 2008 Elsevier B. V. All rights reserved.

引用

页码：389 / 396

页数：8

共 50 条

[1] Synthesis and catalytic activity of nickel(II) complexes of CNC pincer-type N-heterocyclic carbene ligands
Wang, Shuchao
Ren, Fang
Qiu, Yuping
Luo, Meiming
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 788 : 27 - 32
[2] Synthesis and catalytic activity of a pincer-type bis(imidazolin-2-ylidene) nickel(II) complex
Inamoto, Kiyofumi
Kuroda, Jun-ichi
Hiroya, Kou
Noda, Yukio
Watanabe, Masashi
Sakamoto, Takao
ORGANOMETALLICS, 2006, 25 (12) : 3095 - 3098
[3] Synthesis, structure, and catalytic activity of palladium(II) complexes of new CNC pincer-type N-heterocyclic carbene ligands
Wei, Wei
Qin, Yuancheng
Luo, Meiming
Xia, Pingfang
Wong, Man Shing
ORGANOMETALLICS, 2008, 27 (10) : 2268 - 2272
[4] Synthesis and catalytic activity of pincer-type bis(benzimidazolin-2-ylidene) palladium complexes
Hahn, FE
Jahnke, MC
Gomez-Benitez, V
Morales-Morales, D
Pape, T
ORGANOMETALLICS, 2005, 24 (26) : 6458 - 6463
[5] New ruthenium(II) CNC-pincer bis(carbene) complexes: Synthesis and catalytic activity
Poyatos, M
Mata, JA
Falomir, E
Crabtree, RH
Peris, E
ORGANOMETALLICS, 2003, 22 (05) : 1110 - 1114
[6] Pincer-Type Mesoionic Carbene Nickel(II) Complexes: Synthesis, Properties, Reactions, and Catalytic Application to the Suzuki-Miyaura Coupling Reaction of Aryl Bromides
Matsubara, Kouki
Tomomatsu, Kanta
Tajiri, Ayame
Watanabe, Arisa
Koga, Yuji
Ishikawa, Ryuta
Yamada, Yuji
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022, 2022 (10)
[7] Synthesis, characterization and application of pincer-type nickel iminophosphinite complexes
Sanford, Jessica
Dent, Catlin
Masuda, Jason D.
Xia, Aibing
POLYHEDRON, 2011, 30 (06) : 1091 - 1094
[8] Synthesis, characterization, electrochemical behavior, and catalytic activity of cobalt(II) metal complexes with pincer-type methylbenzamide derivative ligands
Keskin, Ebru
Turunc, Ersan
Arslan, Hakan
POLYHEDRON, 2022, 221
[9] Synthesis, Structure, and Reactivity of Nitrosyl Pincer-Type Rhodium Complexes
Gaviglio, Carina
Ben-David, Yehoshoa
Shimon, Linda J. W.
Doctorovich, Fabio
Milstein, David
ORGANOMETALLICS, 2009, 28 (06) : 1917 - 1926
[10] Ruthenium carbene complexes featuring a tridentate pincer-type ligand
Wasilke, JC
Wu, G
Bu, XH
Kehr, G
Erker, G
ORGANOMETALLICS, 2005, 24 (17) : 4289 - 4297

← 1 2 3 4 5 →