Copper telluride (CuTe) nanowires were synthesized electrochemically from aqueous acidic solution of copper (II) sulphate (CuSO4 center dot 5H(2)O) and tellurium oxide (TeO2) on a copper substrate by template-assisted electrodeposition method. The electrodeposition was conducted at 30 A degrees C and the length of nanowires was controlled by adjusting deposition time. Structural characteristics were examined using X-ray diffraction and scanning electron microscope which confirm the formation of CuTe nanowires. Investigation for chemical sensing was carried out using air and chloroform, acetone, ethanol, glycerol, distilled water as liquids having dielectric constants 1, 4 center dot 81, 8 center dot 93, 21, 24 center dot 55, 42 center dot 5 and 80 center dot 1, respectively. The results unequivocally prove that copper telluride nanowires can be fabricated as chemical sensors with enhanced sensitivity and reliability.