The Baylis-Hillman reaction in supercritical carbon dioxide: enhanced reaction rates, unprecedented ether formation, and a novel phase-dependent 3-component coupling

被引：40

作者：

Rose, PM ^{[1
]}

Clifford, AA ^{[1
]}

Rayner, CM ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 09期

关键词：

D O I：

10.1039/b111347j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Baylis-Hillman reaction can be efficiently carried out in scCO(2) with enhanced reaction rates relative to comparable solution phase reactions; at low pressures, a novel dimerisation is observed which has led to the development of a novel one-pot three component coupling reaction to form highly functionalised ethers.

引用

页码：968 / 969

页数：2

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