Vacuum-ultraviolet photodecomposition of stannane

被引：7
作者：
Aaserud, DJ [1 ]
Lampe, FW [1 ]
机构：
[1] PENN STATE UNIV,DEPT CHEM,UNIVERSITY PK,PA 16802
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 24期
关键词：
D O I：
10.1021/jp960740n
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The 147-nm photolysis of SnH4 results in the formation of H-2, Sn(s), and a very small amount of Sn2H6. The quantum yields decrease with increasing partial pressure of SnH4, at 0.2 Torr being Phi(-SnH4) = 5.6 +/- 0.3, Phi(H-2) = 11.4 +/- 0.6, and Phi(Sn2H6) = 0.059 +/- 0.02. A mechanism is proposed that is shown to be internally consistent and in agreement with the experimental facts.
引用
收藏
页码：10215 / 10222
页数：8
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