Vacuum-ultraviolet photodecomposition of stannane

被引：5

作者：

Aaserud, DJ ^{[1
]}

Lampe, FW ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT CHEM,UNIVERSITY PK,PA 16802

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 24期

关键词：

D O I：

10.1021/jp960740n

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The 147-nm photolysis of SnH4 results in the formation of H-2, Sn(s), and a very small amount of Sn2H6. The quantum yields decrease with increasing partial pressure of SnH4, at 0.2 Torr being Phi(-SnH4) = 5.6 +/- 0.3, Phi(H-2) = 11.4 +/- 0.6, and Phi(Sn2H6) = 0.059 +/- 0.02. A mechanism is proposed that is shown to be internally consistent and in agreement with the experimental facts.

引用

页码：10215 / 10222

页数：8

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