A new heterocycle, 2 lambda(3),4 lambda(5)-[1,2,4]-oxadiphosphinine (2), as ligand of a binuclear iron complex

被引：1
作者：
Rosche, F
Heckmann, G
Weller, F
Fluck, E
机构：
[1] MAX PLANCK GESELL,GMELIN INST ANORGAN CHEM & GRENZGEBIETE,D-60486 FRANKFURT,GERMANY
[2] UNIV STUTTGART,INST ANORGAN CHEM,D-70569 STUTTGART,GERMANY
[3] UNIV MARBURG,FACHBEREICH CHEM,D-35043 MARBURG,GERMANY
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1996年 / 51卷 / 12期
关键词：
1,2,4]-oxadiphosphinine; binuclear iron complex; NMR spectra; X-ray;
D O I：
10.1515/znb-1996-1209
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Preparation and properties of a coordination compound are described, in which a carbonyl group in bis[(dicarbonyl)(eta(5)-cyclopentadienyl)iron] is substituted by hitherto unknown octa-N-methyl 2 lambda(3),4 lambda(5)-[1,2,4]-oxadiphosphinine-2,4,4, 6-tetramine (2). The H-1, P-31, and C-13 NMR spectra are recorded and discussed in detail. The molecular structure of the iron complex 4 is described and interpreted.
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页码：1725 / 1731
页数：7
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