Ion-molecule reactions for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a tandem mass spectrometer

被引：11

作者：

Fu, Mingkun ^{[1
]}

Duan, Penggao ^{[1
]}

Gao, Jinshan ^{[1
]}

Kenttaemaa, Hilkka I. ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

来源：

ANALYST | 2012年 / 137卷 / 24期

基金：

美国国家科学基金会;

关键词：

INDUCED DISSOCIATION; IDENTIFICATION; STRATEGIES;

D O I：

10.1039/c2an35986c

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A mass spectrometric method utilizing gas-phase ion-molecule reactions of 1-butanethiol and di-tert-butyl peroxide has been developed for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a FT-ICR mass spectrometer.

引用

页码：5720 / 5722

页数：3

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