Ion-molecule reactions for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a tandem mass spectrometer

被引：11
|
作者：
Fu, Mingkun [1 ]
Duan, Penggao [1 ]
Gao, Jinshan [1 ]
Kenttaemaa, Hilkka I. [1 ]
机构：
[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA
来源：
ANALYST | 2012年 / 137卷 / 24期
基金：
美国国家科学基金会;
关键词：
INDUCED DISSOCIATION; IDENTIFICATION; STRATEGIES;
D O I：
10.1039/c2an35986c
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A mass spectrometric method utilizing gas-phase ion-molecule reactions of 1-butanethiol and di-tert-butyl peroxide has been developed for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a FT-ICR mass spectrometer.
引用
收藏
页码：5720 / 5722
页数：3
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