Exchange chemistry of tBu3P(CO2)B(C6F5)2Cl

被引：37
作者：
Neu, Rebecca C. [1 ]
Menard, Gabriel [1 ]
Stephan, Douglas W. [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 30期
基金：
加拿大自然科学与工程研究理事会;
关键词：
FRUSTRATED LEWIS PAIRS; CO2; BINDING;
D O I：
10.1039/c2dt30206c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Halide exchange from the species tBu(3)P(CO2)B(C6F5)(2)Cl 1 with Me3SiOSO2CF3 gave tBu(3)P(CO2)B(C6F5)(2)(OSO2CF3) 2. Similarly, Lewis acid exchange occurs in reactions of 1 with Al(C6F5)(3) and [Cp2TiMe][B(C6F5)(4)] affording the products, tBu(3)P(CO2)Al(C6F5)(3) 3 and [tBu(3)P(CO2)TiCp2Cl][B(C6F5)(4)] 4.
引用
收藏
页码：9016 / 9018
页数：3
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