Study on activities of vanadium (IV/V) doped TiO2(R) nanorods induced by UV and visible light

被引:91
作者
Li, Li [1 ,2 ,3 ]
Liu, Chun-yan [1 ]
Liu, Yun [1 ]
机构
[1] Chinese Acad Sci, Key Lab Photochem Convers, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Optoelect Mat Tech Inst Phys & Chem, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Grad Sch, Beijing 100806, Peoples R China
关键词
Nanostructures; Chemical synthesis; Nanorod rutile; Surface properties; TITANIUM-DIOXIDE PHOTOCATALYSTS; THIN-FILM PHOTOCATALYSTS; AQUEOUS-SOLUTIONS; IRRADIATION; NANOPARTICLES; ANATASE; RUTILE; OXIDE; PHOTODEGRADATION; DISPERSIONS;
D O I
10.1016/j.matchemphys.2008.08.009
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Vanadium (IV/V) doped rutile TiO2 naonorods had been successfully synthesized through a single step hydrothermal method. The photocatalyst was characterized by transmission electron microscopy (TEM), selected area electron diffraction (SAED), high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), UV-vis diffusive reflectance spectroscopy (DRS) and X-ray photoelectron spectroscopy (XPS). The results showed that the doping of V ions had significant influence on the band gap energy and the surface state of TiO2. The photo-activities of the new catalysts were investigated under ultraviolet (UV) and visible light. The UV-photocatalytic activity of the as-prepared catalysts was hardly influenced by doping V ions: while under visible light, the samples with 1 wt% and 0.1 wt% V exhibited enhanced activity to the oxidation of methylene blue (MB) and the reduction of Cr (VI), respectively. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:551 / 557
页数:7
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