Identification of 5-Hydroxy-3-mercapto-2-pentanone in the Maillard Reaction of Thiamine, Cysteine, and Xylose

被引:10
作者
Cerny, Christoph [1 ]
Guntz-Dubini, Renee [1 ]
机构
[1] Firmenich Co, Corp R&D Div, CH-1217 Geneva 2, Switzerland
关键词
Maillard reaction; thiamine; cysteine; xylose; 5-hydroxy-3-mercapto-2-pentanone; NMR;
D O I
10.1021/jf801762c
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
5-Hydroxy-3-mercapto-2-pentanone is claimed in the scientific literature as a key intermediate in the degradation of thiamine and the related generation of aroma compounds; however, there are no analytical NMR and MS data available. We have identified the compound in a thermally treated mixture of thiamine, cysteine, and xylose and characterized it by MS and NMR.
引用
收藏
页码:10679 / 10682
页数:4
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