A Novel 3-D Cobalt-Organic Framework Constructed by 2-Ethyl-1H-imidazole-4,5-dicarboxylic Acid and 4,4′-Bipyridine

被引：4
|
作者：
Jia, Hongliang [1 ,2 ]
Guo, Mengwei [1 ]
Ma, Bing [1 ]
Liu, Ying [1 ]
Li, Gang [1 ]
机构：
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
[2] Zhengzhou Kindergarten Teachers Coll, Zhengzhou, Henan, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 10期
基金：
中国国家自然科学基金;
关键词：
crystal structure; metal-organic framework; synthesis; thermal property; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; HELICAL CHAINS; LAYERS;
D O I：
10.1080/15533174.2012.762785
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel coordination polymer, namely {[Co-3(HEIDC)(2)(4,4-bipy)(3)]2NO(3)6H(2)O}(n) (1), has been hydrothermally successfully synthesized by the reaction of 2-ethyl-1H-imidazole-4,5-dicarboxylic acid (H3EIDC) with Co(NO3)(2)6H(2)O in the presence of 4,4-bipyridine (4,4-bipy). The single-crystal structural study reveals that 1 is a 3D metal-organic framework, which can be viewed as made up of [Co-3(HEIDC)(2)(4,4-bipy)(3)](n) units, nitrate anions and solvent water molecules. Its thermal properties have been determined as well.
引用
收藏
页码：1458 / 1464
页数：7
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