Formation of amino-terminated self-assembled monolayers from long-chain aminomethoxylsilanes

被引：5
作者：
Liu, Lei [1 ]
Song, Shiyong [1 ,2 ]
Zhang, Pingyu [2 ]
机构：
[1] Henan Univ, Inst Pharmaceut, Kaifeng 475004, Peoples R China
[2] Minist Educ, Key Lab Special Funct Mat, Kaifeng, Henan, Peoples R China
来源：
SURFACE AND INTERFACE ANALYSIS | 2013年 / 45卷 / 06期
基金：
中国国家自然科学基金;
关键词：
reaction time; water content; XPS; RAY PHOTOELECTRON-SPECTROSCOPY; SILICON SURFACE; OXIDE SURFACES; FUNCTIONALIZATION; SILANIZATION; 3-AMINOPROPYLTRIETHOXYSILANE; OCTADECYLTRICHLOROSILANE; SI(100); SILANE; COPPER;
D O I：
10.1002/sia.5197
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
3-Aminopropyltriethoxylsilane (APS), N-[3-(Trimethoxylsilyl)propyl]-ethylenediamine, N-[3-(Trimethoxylsilyl) propyl]diethyenetriamine were assembled onto silicon surfaces. Using a mixture of acetone and water as solvent, factors which would affect the formation of amino-terminated self-assembled monolayers (SAMs), such as water content in solvent and reaction time, were investigated. The structural information of SAMs was collected from contact angle measurements, ellipsometric thickness measurements and X-ray photoelectronic spectroscopy. Reaction time and water content in solvent produced dominant effects on the formation of amino terminated SAMs. The method introduced in this paper also presents a simple and controllable way to prepare amino-terminated SAMS. Copyright (C) 2012 John Wiley & Sons, Ltd.
引用
收藏
页码：993 / 997
页数：5
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