Kinetics of propylene epoxidation with hydrogen peroxide

被引：11

作者：

Danov, S. M. ^{[1
]}

Sulimov, A. V. ^{[1
]}

Kolesnikov, V. A. ^{[1
]}

Ovcharov, A. A. ^{[1
]}

机构：

[1] Nizhnii Novgorod State Tech Univ, Dzerzhinsk Polytech Inst, Dzerzhinsk 606026, Nizhegorodskaya, Russia

来源：

KINETICS AND CATALYSIS | 2013年 / 54卷 / 02期

关键词：

Equilibrium constants - Propylene - Rate constants - Titanium oxides - Zeolites;

D O I：

10.1134/S0023158413020031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of propylene oxidation to propylene oxide in the presence of a titanium-containing zeolite in an isopropyl alcohol medium is reported. The influence of the concentrations of the starting substances and reaction products and temperature on the rate of the process is considered. A mathematical model has been derived from the experimental data obtained. The rate constants, adsorption equilibrium constants, and activation energies of the reactions have been calculated.

引用

页码：193 / 198

页数：6