Conductivity of LiBOB in Various Ternary Solvent Blends and the Electrochemical Performance of LiBOB-PC/EMC/DMC Used in Li/MCMB and LiFePO4/Li Cells

被引：11

作者：

Li, S. Y. ^{[1
,2
]}

Ma, P. H. ^{[1
]}

Song, S. T. ^{[1
,2
]}

Ren, Q. D. ^{[1
,2
]}

Li, F. Q. ^{[1
]}

机构：

[1] Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2008年 / 44卷 / 10期

关键词：

LiBOB; conductivity; LiFePO4; MCMB;

D O I：

10.1134/S1023193508100091

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The solid-state reaction was employed to obtain LiBOB in vacuum dryer at 100 degrees C, with the dryer of P2O5. The resulting LiBOB was employed in various ternary solvent blends to get the k, and its change with salt, solvent composition and temperature. 0.7 M LiBOB-PC/EMC/DMC (1: 1: 1, v: v: v) and 0.5 M LiBOB-EC/EMC/DMC (1: 1: 1, v: v: v) were observed to have better k at wide theta range, and the former was chosen to assemble Li/MCMB and LiFePO4/Li cells. The results indicated that it can stabilize the MCMB anodes, and exhibit good stability in LiFePO4/Li cell.

引用

页码：1144 / 1148

页数：5

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