Electrochemical Valorisation of Glycerol

被引:280
作者
Simoes, Mario [1 ]
Baranton, Steve [1 ]
Coutanceau, Christophe [1 ]
机构
[1] Univ Poitiers, IC2MP, CNRS, UMR 7285, F-86022 Poitiers, France
关键词
electrochemistry; energy conversion; heterogeneous catalysis; hydrogen; palladium; ANION-EXCHANGE MEMBRANE; ALCOHOL FUEL-CELLS; OXYGEN EVOLUTION REACTION; AD-ATOM ELECTRODES; ELECTROCATALYTIC OXIDATION; ALKALINE-MEDIUM; ETHYLENE-GLYCOL; HYDROGEN-PRODUCTION; PLATINUM-ELECTRODES; METHANOL OXIDATION;
D O I
10.1002/cssc.201200335
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The worldwide glycerol stocks are increasing; to make the biodiesel industry sustainable economically, this chemical could be used as a secondary primary raw material. Electric energy or hydrogen and added-value-chemical cogeneration becomes more and more an important research topic for increasing economical and industrial interests towards electrochemical technologies. Studies on glycerol electrooxidation for fuel or electrolysis cell applications are scarce. The valorisation of glycerol is generally performed by organic chemistry reactions forming, for example, esters, glycerol carbonates, ethers, acetals or ketals. Glycerol oxidation is made up of complex pathway reactions that can produce a large number of useful intermediates or valuable fine chemicals with presently limited market impact due to expensive production processes. Many of these chemical oxidation routes lead to significant amounts of undesired by-products, and enzymatic processes are limited. Converse to classical heterogeneous processes, electrocatalytic oxidation processes can be tuned by controlling the nature, composition and structure of the electrocatalyts as well as the electrode potential. Such control may lead to very high selectivity and activity, avoiding or limiting product separation steps. The coupling of glycerol oxidation to produce chemicals with the oxygen reduction reaction in a fuel cell or water reduction reaction in an electrolysis cell on Pt-free catalysts results either in coproduction of electrical energy or hydrogen for energy storage.
引用
收藏
页码:2106 / 2124
页数:19
相关论文
共 124 条
[1]   A thermodynamic analysis of hydrogen production by steam reforming of glycerol [J].
Adhikari, Sushil ;
Fernando, Sandun ;
Gwaltney, Steven R. ;
To, S. D. Filip ;
Bricka, R. Mark ;
Steele, Philip H. ;
Haryanto, Agus .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (14) :2875-2880
[2]  
ADZIC RR, 1986, J CATAL, V101, P532
[3]   Fuel cells for chemicals and energy cogeneration [J].
Alcaide, F ;
Cabot, PL ;
Brillas, E .
JOURNAL OF POWER SOURCES, 2006, 153 (01) :47-60
[4]   Synergistic temperature and ethanol effect on Saccharomyces cerevisiae dynamic behaviour in ethanol bio-fuel production [J].
Aldiguier, AS ;
Alfenore, S ;
Cameleyre, X ;
Goma, G ;
Uribelarrea, JL ;
Guillouet, SE ;
Molina-Jouve, C .
BIOPROCESS AND BIOSYSTEMS ENGINEERING, 2004, 26 (04) :217-222
[5]   Hydrogen production from glycerol steam reforming for low- and high-temperature PEMFCs [J].
Authayanun, Suthida ;
Arpornwichanop, Amornchai ;
Patcharauorachot, Yaneeporn ;
Wiyaratn, Wisitsree ;
Assabumrungrat, Suttichai .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (01) :267-275
[6]   ADSORPTION OF GLYCEROL ON PLATINUM IN ALKALINE-MEDIUM - EFFECT OF THE ELECTRODE STRUCTURE [J].
AVRAMOVIVIC, M ;
LEGER, JM ;
BEDEN, B ;
HAHN, F ;
LAMY, C .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 351 (1-2) :285-297
[7]   THE ELECTROOXIDATION OF GLYCEROL ON THE GOLD(100)-ORIENTED SINGLE-CRYSTAL SURFACE AND POLYCRYSTALLINE SURFACE IN 0.1 M NAOH [J].
AVRAMOVIVIC, ML ;
LEGER, JM ;
LAMY, C ;
JOVIC, VD ;
PETROVIC, SD .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 308 (1-2) :309-317
[8]   Single-site and nanosized Fe-Co electrocatalysts for oxygen reduction: Synthesis, characterization and catalytic performance [J].
Bambagioni, Valentina ;
Bianchini, Claudio ;
Filippi, Jonathan ;
Lavacchi, Alessandro ;
Oberhauser, Werner ;
Marchionni, Andrea ;
Moneti, Simonetta ;
Vizza, Francesco ;
Psaro, Rinaldo ;
Dal Santo, Vladimiro ;
Gallo, Alessandro ;
Recchia, Sandro ;
Sordelli, Laura .
JOURNAL OF POWER SOURCES, 2011, 196 (05) :2519-2529
[9]  
Bambagioni V, 2010, CHIM OGGI, V28, pVII
[10]   Self-Sustainable Production of Hydrogen, Chemicals, and Energy from Renewable Alcohols by Electrocatalysis [J].
Bambagioni, Valentina ;
Bevilacqua, Manuela ;
Bianchini, Claudio ;
Filippi, Jonathan ;
Lavacchi, Alessandro ;
Marchionni, Andrea ;
Vizza, Francesco ;
Shen, Pei Kang .
CHEMSUSCHEM, 2010, 3 (07) :851-855