Catalytic Properties of Sb-SnO2/Ti Electrode Doped by Europium Salt with Different Anions

被引:0
作者
Liu Chao [1 ]
Li Huaixiang [1 ,2 ]
Shen Chongyin [1 ]
机构
[1] Shandong Normal Univ, Jinan 250014, Peoples R China
[2] Shandong Key Lab Clean Prod Fine Chem, Jinan 250014, Peoples R China
关键词
anion effect; europium salt; composite electrode; electrocatalytic degradation; ELECTROCHEMICAL DEGRADATION; METHYLENE-BLUE; OXIDATION; PHENOL; NANOPARTICLES; PATHWAYS; FILMS; OXIDE; XPS;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
EuBr3, Eu(NO3)(3), EuCl3, Eu(ClO4)(3), Eu(AC)(3) doped Sb-SnO2/Ti electrodes were prepared by thermal decomposition. The properties of electrodes for the oxidation of ethanol and the electro-catalytic decomposition of a model pollutant (methyl orange, methylene blue) were investigated. Electrodes were characterized by cyclic voltammetry, X-ray diffraction, scanning electron microscope, and X-ray photoelectron spectroscopy. It is suggested that various Eu salts doped Sb-SnO2/Ti electrodes show different catalytic properties. Eu(ClO4)(3) doped electrodes show the best effect for degradation of methyl orange, EuCl3 doped electrodes provide the best degradation of methylene blue, and as for electric catalytic oxidation ethanol, Eu (NO3)(3) doped electrodes show the highest catalytic activity.
引用
收藏
页码:2362 / 2366
页数:5
相关论文
共 30 条
[1]   Particle Size Effect of Unsupported Pt/SnOx Nanoparticles for Ethanol Electro-Oxidation [J].
Baranova, Elena A. ;
Tavasoli, Alexandra ;
Amir, Tariq .
ELECTROCATALYSIS, 2011, 2 (02) :89-95
[2]   Parallel pathways of ethanol oxidation: The effect of ethanol concentration [J].
Camara, GA ;
Iwasita, T .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 578 (02) :315-321
[3]   Improving the stability of Sb doped Sn oxides electrode thermally synthesized by using an acid ionic liquid as solvent [J].
Carlesi Jara, Carlos ;
Salazar-Banda, Giancarlo Richard ;
Schrebler Arratia, Rodrigo ;
Silva Campino, Javier ;
Irrazabal Aguiler, Maik .
CHEMICAL ENGINEERING JOURNAL, 2011, 171 (03) :1253-1262
[4]   Electrochemical behavior of novel Ti/IrOx-Sb2O5-SnO2 anodes [J].
Chen, GH ;
Chen, XM ;
Yue, PL .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (17) :4364-4369
[5]   Effect of univalent cations fluoride in F-Sb codoped SnO2 electrode on electro-catalytic degradation of methyl orange [J].
Chen, Lu-Sheng ;
Liu, Yan-Yan ;
Li, Huai-Xiang ;
Liu, Chao ;
Wu, Kang .
ADVANCED IN NANOSCIENCE AND TECHNOLOGY, 2012, 465 :192-+
[6]   Influence of rare earths doping on the structure and electro-catalytic performance of Ti/Sb-SnO2 electrodes [J].
Cui, Yu-Hong ;
Feng, Yu-Jie ;
Liu, Zheng-Qian .
ELECTROCHIMICA ACTA, 2009, 54 (21) :4903-4909
[7]   On the behaviour of doped SnO2 anodes stabilized with platinum in the electrochemical degradation of reactive dyes [J].
del Rio, A. I. ;
Fernandez, J. ;
Molina, J. ;
Bonastre, J. ;
Cases, F. .
ELECTROCHIMICA ACTA, 2010, 55 (24) :7282-7289
[8]   Electro-catalytic oxidation of phenol on several metal-oxide electrodes in aqueous solution [J].
Feng, YJ ;
Li, XY .
WATER RESEARCH, 2003, 37 (10) :2399-2407
[9]   Factors affecting the electro-catalytic characteristics of Eu doped SnO2/Sb electrode [J].
Feng, Yujie ;
Cui, Yu-Hong ;
Liu, Junfeng ;
Logan, Bruce E. .
JOURNAL OF HAZARDOUS MATERIALS, 2010, 178 (1-3) :29-34
[10]   Preparation and application of pharmaceutical wastewater treatment by praseodymium doped SnO2/Ti electrocatalytic electrode [J].
Han Guocheng ;
Liu Zheng ;
Wang Yongliao .
JOURNAL OF RARE EARTHS, 2008, 26 (04) :532-537