Phase Behavior and Microstructure of Microemulsions Containing the Hydrophobic Ionic Liquid 1-Butyl-3-methylimidazolium Hexafluorophosphate

被引：47

作者：

Anjum, Nishat ^{[1
,2
]}

Guedeau-Boudeville, Marie-Alice ^{[1
,2
]}

Stubenrauch, Cosima ^{[3
]}

Mourchid, Ahmed ^{[1
,2
]}

机构：

[1] CNRS, UMR 7057, MSC, F-75205 Paris 13, France

[2] Univ Paris Diderot, F-75205 Paris 13, France

[3] Univ Coll Dublin, Sch Chem & Bioproc Engn, Dublin 4, Ireland

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2009年 / 113卷 / 01期

关键词：

ANGLE NEUTRON-SCATTERING; TERNARY-SYSTEMS; POLAR; WATER; SOLUBILITY; MIXTURES;

D O I：

10.1021/jp808643s

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The phase behavior and microstructure of the ternary system water/1-butyl-3-methylimidazolium hexafluorophosphate (bmimPF(6))/Triton X-100 was studied as a function of temperature and ionic liquid (IL) mass fraction a. In the present study, a hydrophobic IL instead of commonly used organic solvents such as n-alkanes is used. The fish-shaped region is distorted at low and high values of alpha, whereas it is symmetric at intermediate alpha. With increasing alpha, the extension of the three-phase region decreases regarding the surfactant concentration range, whereas it increases regarding the temperature range. For comparison the phase behavior of two ternary water/bmimPF(6)/alkyl oligoethyleneoxide (CiEj) systems has been investigated. Our results are compared with those obtained for water/n-alkane/CiEj and IL/n-alkane/CiEj systems, respectively.

引用

页码：239 / 244

页数：6

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