Facile synthesis of nitrogen-doped carbon coated CoSnO3 via hydrothermal carbonization of carboxylated chitosan as anode materials for lithium-ion batteries

被引:34
作者
Fang, Guoqing [1 ]
Kaneko, Shingo [1 ]
Liu, Weiwei [1 ]
Xia, Bingbo [1 ]
Sun, Hongdan [1 ]
Zhang, Ruixue [1 ]
Zheng, Junwei [1 ]
Li, Decheng [1 ]
机构
[1] Soochow Univ, Inst Chem Power Sources, Key Lab Lithium Battery Mat Jiangsu Prov, Suzhou 215006, Peoples R China
关键词
Lithium ion battery; Nitrogen-doped carbon; CoSnO3; Anode material; NEGATIVE-ELECTRODE MATERIALS; ELECTROCHEMICAL PERFORMANCE; STORAGE CAPABILITY; TIN; NANOMATERIALS; COMPOSITES; LI4TI5O12; CASNO3; OXIDE;
D O I
10.1016/j.apsusc.2013.07.053
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
N-doped carbon coated CoSnO3 composite (CoSnO3@N-C) is reported here as a high capacity anode material for lithium-ion battery for the first time. CoSnO3@N-C is synthesized by a simple hydrothermal reaction of carboxylated chitosan and subsequent carbonization approach. The CoSnO3@N-C material exhibited enhanced lithium storage property and cyclic performance delivering a reversible capacity of 650 mAh g(-1) after 50 cycles at 100 mAg(-1), compared to bare CoSnO3.Morewhile, the CoSnO3@N-C electrode also showed remarkable rate performance. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:963 / 967
页数:5
相关论文
共 25 条
[1]   Nanomaterials for rechargeable lithium batteries [J].
Bruce, Peter G. ;
Scrosati, Bruno ;
Tarascon, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946
[2]   SnO2-Based Nanomaterials: Synthesis and Application in Lithium-Ion Batteries [J].
Chen, Jun Song ;
Lou, Xiong Wen .
SMALL, 2013, 9 (11) :1877-1893
[3]   Towards understanding the effects of carbon and nitrogen-doped carbon coating on the electrochemical performance of Li4Ti5O12 in lithium ion batteries: a combined experimental and theoretical study [J].
Ding, Zijing ;
Zhao, Liang ;
Suo, Liumin ;
Jiao, Yang ;
Meng, Sheng ;
Hu, Yong-Sheng ;
Wang, Zhaoxiang ;
Chen, Liquan .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (33) :15127-15133
[4]   Challenges for Rechargeable Li Batteries [J].
Goodenough, John B. ;
Kim, Youngsik .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :587-603
[5]   Synthesis, characterization of core-shell carbon-coated CaSnO3 nanotubes and their performance as anode of lithium ion battery [J].
Hu, Xiaoyan ;
Xiao, Ting ;
Huang, Wei ;
Tao, Wei ;
Heng, Bojun ;
Chen, Xinqi ;
Tang, Yiwen .
APPLIED SURFACE SCIENCE, 2012, 258 (17) :6177-6183
[6]   Synthesis and electrochemical performance of nanosized magnesium tin composite oxides [J].
Huang, F ;
Yuan, ZY ;
Zhan, H ;
Zhou, YH ;
Sun, JT .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 83 (01) :16-22
[7]   A novel tin-based nanocomposite oxide as negative-electrode materials for Li-ion batteries [J].
Huang, F ;
Yuan, ZY ;
Zhan, H ;
Zhou, YH ;
Sun, JT .
MATERIALS LETTERS, 2003, 57 (22-23) :3341-3345
[8]  
Kumar MNVR, 2000, REACT FUNCT POLYM, V46, P1
[9]   Fermi energy level tuning for high performance dye sensitized solar cells using sp2 selective nitrogen-doped carbon nanotube channels [J].
Lee, Ga In ;
Nath, Narayan Chandra Deb ;
Sarker, Subrata ;
Shin, Weon Ho ;
Ahammad, A. J. Saleh ;
Kang, Jeung Ku ;
Lee, Jae-Joon .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (15) :5255-5259
[10]   Nitrogen-doped carbon coated Li4Ti5O12 nanocomposite: Superior anode materials for rechargeable lithium ion batteries [J].
Li, Hongsen ;
Shen, Laifa ;
Zhang, Xiaogang ;
Wang, Jie ;
Nie, Ping ;
Che, Qian ;
Ding, Bing .
JOURNAL OF POWER SOURCES, 2013, 221 :122-127