Low-Transition-Temperature Mixtures (LTTMs): A New Generation of Designer Solvents

被引：1112

作者：

Francisco, Maria ^{[1
]}

van den Bruinhorst, Adriaan ^{[1
]}

Kroon, Maaike C. ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Dept Chem Engn & Chem, NL-5612 AZ Eindhoven, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 11期

关键词：

deep-eutectic solvents; green solvents; hydrogen bonds; separation processes; solvent design; DEEP-EUTECTIC-SOLVENTS; IONIC LIQUIDS; CHOLINE-CHLORIDE; GREEN SOLVENT; VISCOSITY; ACID; DENSITY; ANALOGS; ROLES; UREA;

D O I：

10.1002/anie.201207548

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new generation of designer solvents emerged in the last decade as promising green media for multiple applications, including separation processes: the low-transition-temperature mixtures (LTTMs). They can be prepared by mixing natural high-melting-point starting materials, which form a liquid by hydrogen-bond interactions. Among them, deep-eutectic solvents (DESs) were presented as promising alternatives to conventional ionic liquids (ILs). Some limitations of ILs are overcome by LTTMs, which are cheap and easy to prepare from natural and readily available starting materials, biodegradable, and renewable. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3074 / 3085

页数：12

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