Synthesis of (E)-2-chlorovinyltellurium trichloride and (E,E)-bis(2-chlorovinyl) ditelluride

被引：17

作者：

Potapov, V. A. ^{[1
]}

Musalova, M. V. ^{[1
]}

Amosova, S. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2012年 / 61卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

acetylene; tellurium tetrachloride; 2-chlorovinyltellurium trichloride; bis(2-chlorovinyl) ditelluride; electrophilic addition; reduction; organotellurium compounds; TELLURIUM TETRACHLORIDE;

D O I：

10.1007/s11172-012-0028-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of tellurium tetrachloride with acetylene in CCl4 at atmospheric pressure and ambient temperature affords earlier unknown (E)-2-chlorovinyltellurium trichloride in 30% yield, whose reduction with sodium bisulfite gives (E,E)-bis(2-chlorovinyl) ditelluride in 64% yield.

引用

页码：204 / 205

页数：2

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