Oxidative in situ deposition of conductive PEDOT:PTSA on textile substrates and their application as textile heating element

Conductive organic polymers are outstanding materials with exciting properties. Besides several other applications - especially in the field of high-performance electric devices and photovoltaic technology they can be used for the creation of conductive textile materials. Commercial dispersions of such polymers can be applied to textile constructions in a downstream coating process leading to poor add-ons and relatively low conductivity. In contrast, the authors have developed strategies to deposit conductive polymers by an oxidative in situ polymerization directly on the textile surface. Here, poly(3,4-ethylene dioxythiophene) p-toluenesulfonic acid (PEDOT:PTSA) was durably immobilized on a textile polyester fleece following this new approach. The extremely high achievable add-ons lead to extraordinary high-conductive textiles with surface resistances down to 10 Omega/sq. Such a way finished textiles can be used as high-performance textile heating elements. For example, by applying a standard voltage of 24V temperatures up to 170 degrees C are practicable. Moreover, the desired temperature is easily adjustable by the absolute load and the applied voltage. These conductive textiles can be used, e.g., in carpets, electric blankets or automotive seat heaters. (C) 2012 Elsevier B.V. All rights reserved.